Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
This calx of Iron has the singular property of flowing in the fire
with somewhat less difficulty than Iron itself; whereas every other
metalline calx flows with less ease than the metal that produced it. It
has moreover the remarkable property of uniting with the phlogiston,
and of being reduced to Iron without fusion; requiring for that purpose
only to be made red-hot.
Iron may be incorporated with Silver, and even with Gold, by means of
certain operations. Under the article of Lead we shall see how it may
be separated from these metals.
The acids produce on it much the same effects as on Copper; every one
of them acts upon it. Certain neutral salts, alkalis, and even water
itself, are capable of dissolving it; and hence it is also very subject
to rust. The vitriolic acid dissolves it with the greater ease: but
the circumstances which attend the solution thereof are different from
those with which the same Acid dissolves Copper: for, 1. whereas the
vitriolic acid must be concentrated to dissolve Copper, it must on
the contrary be diluted with water to dissolve Iron, which it will
not touch when well dephlegmated. 2. The vapours which rise in this
dissolution are inflammable; so that if it be made in a small-necked
bottle, and the flame of a candle be applied to the mouth thereof, the
vapours in the bottle take fire with such rapidity as to produce a
considerable explosion.
This solution is of a beautiful green colour; and from this union of
the vitriolic acid with Iron there results a neutral metalline salt,
which has the property of shooting into crystals of a rhomboidal
figure, and a green colour. These crystals are called _Green Vitriol_,
_Vitriol of Mars_, and _Copperas_.
Green Vitriol hath a saltish and astringent taste. As it retains a
great deal of water in crystallizing, it quickly flows by the action
of fire: but this fluidity is owing to its water only, and is not a
real fusion; for, as soon as its moisture is evaporated, it resumes a
solid form. Its green transparent colour is now changed into an opaque
white: and, if the calcination be continued, its acid also exhales and
is dissipated in vapours; and as it loses that, it turns gradually to
a yellow colour, which comes so much the nearer to a red the longer
the calcination is continued, or the higher the force of the fire is
raised; which being driven to the utmost, what remains is of a very
deep red. This remainder is nothing but the body of the Iron, which
having lost its phlogiston is now no more than an earth, nearly of the
same nature with that which is left after calcining the metal itself.
Green Vitriol dissolved in water spontaneously lets fall a yellowish
earthy sediment. If this solution be defecated by filtration, it still
continues to deposite some of the same substance, till the vitriol be
wholly decomposed. This sediment is nothing but the earth of Iron,
which is then called _Ochre_.
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