Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Water also acts upon Iron; and therefore Iron exposed to moisture grows
rusty. If iron-filings be exposed to the dew, they turn wholly to a
rust, which is called _Crocus Martis Aperiens_.
Iron exposed to the fire together with nitre makes it detonate pretty
briskly, sets it in a flame, and decomposes it with rapidity.
This metal hath a greater affinity than any other metalline substance
with sulphur; on which account it is successfully used to precipitate
and separate all metalline substances combined with sulphur.
Sulphur uniting with Iron communicates to it such a degree of
fusibility, that if a mass of this metal heated red-hot be rubbed with
a bit of sulphur, it incessantly runs into as perfect a fusion as a
metal exposed to the focus of a large burning-glass.
SECTION V.
_Of_ TIN.
Tin is the lightest of all metals. Though it yields easily to the
impression of hard bodies, it has but little ductility. Being bent
backwards and forwards it makes a small crackling noise. It flows with
a very moderate degree of fire, and long before it comes to be red-hot.
When it is in fusion, its surface soon grows dusty, and there forms
upon it a thin dark-coloured dusty pellicle, which is no other than a
part of the Tin that has lost its phlogiston, or a calx of Tin. The
metal thus calcined easily recovers its metalline form on the addition
of a phlogiston. If the calx of Tin be urged by a strong fire it grows
white, but the greatest violence of heat will not fuse it; which makes
some Chymists consider it as a calcinable or absorbent earth, rather
than a vitrifiable one. Yet it turns to glass, in some sort, when mixed
with any other substance that vitrifies easily. However, it always
produces an imperfect glass only, which is not at all transparent, but
of an opaque white. The calx of Tin thus vitrified is called _Enamel_.
Enamels are made of several colours by the addition of this or that
metalline calx.
Tin unites easily with all the metals; but it destroys the ductility
and malleability of every one of them, Lead excepted. Nay, it possesses
this property of making metals brittle in such an eminent degree, that
the very vapour of it, when in fusion, is capable of producing this
effect. Moreover, which is very singular, the most ductile metals, even
Gold and Silver, are those on which it works this change with the most
ease, and in the greatest degree. It has also the property of making
Silver mixed with it flow over a very small fire.
It adheres to, and in some measure incorporates with, the surface of
Copper and of Iron; whence arose the practice of coating over those
metals with Tin. Tin plates are no other than thin plates of Iron
tinned over.
If to twenty parts of Tin one part of Copper be added, this alloy
renders it much more solid, and the mixed mass continues tolerably
ductile.
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