Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
If spirit of salt, or even sea-salt in substance, be added to a
solution of Lead in the nitrous acid, a white precipitate immediately
falls; which is no other than the Lead united with the marine acid.
This precipitate is extremely like the precipitate of Silver made in
the same manner, and that being called _Luna cornea_ hath occasioned
this to be named _Plumbum corneum_. Like the _luna cornea_ it is
very fusible, and being melted hardens like it into a kind of horny
substance: it is volatile, and may be reduced by means of inflammable
matters combined with alkalis. But it differs from the _luna cornea_
in this chiefly, that it dissolves easily in water; whereas the _luna
cornea_, on the contrary, dissolves therein with great difficulty, and
in a very small quantity.
As this precipitation of Lead from its solution in spirit of nitre is
procured by the marine acid, Lead is thereby proved to have a greater
affinity with the latter acid than with the former. Yet, if you attempt
to dissolve Lead directly by the acid of sea-salt, the solution is
not so easily effected as by the spirit of nitre, and it is always
imperfect; for it wants one of the conditions essential to every
solution in a liquor, namely transparency.
If Lead be boiled for a long time in a lixivium of fixed alkali, part
of it will be dissolved.
Sulphur renders this metal refractory and scarce fusible; and the
mass they form when united together is friable. Hence it appears that
sulphur acts upon Lead much in the same manner as upon Tin; that is, it
renders both these metals less fusible, which are naturally the most
fusible of any, while it exceedingly facilitates the fusion of Silver,
Copper, and Iron, metals which of themselves flow with the greatest
difficulty.
CHAP. VIII.
_Of_ QUICK-SILVER.
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