Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
It will be shewn in its proper place, that almost every vegetable
matter, as well as Tartar, leaves a fixed alkali in its ashes: yet
Tartar has these peculiar properties; first, it assumes an alkaline
character even when burnt or calcined in close vessels, whereas other
substances acquire it only by being burnt in the open air; secondly,
the alkali of Tartar is stronger and more saline than almost any that
is obtained from other matters.
This alkali, when thoroughly calcined, powerfully attracts the moisture
of the air, and melts into an unctuous alkaline liquor, improperly
called _Oil of Tartar per deliquium_. This is the alkali generally used
in making the _Terra Foliata_, mentioned under the head of Vinegar;
for which reason this combination is called _Terra Foliata Tartari_; a
name suitable enough. But the same cannot be said of the other name,
_Regenerated Tartar_, which is also given it. It is true, that on this
occasion an oily acid is restored to the earth of the Tartar, analagous
to that of which the fire had deprived it: but the compound thence
resulting is a neutral salt which very readily dissolves in water;
whereas Tartar is manifestly acid, and not soluble, or at least hardly
soluble, in water.
Crystals of Tartar combined with alkali of Tartar produce a great
effervescence while they are mixing, as all acids usually do; and if
the combination be brought exactly up to the point of saturation, a
perfectly neutral salt is formed, which shoots into crystals, and
easily dissolves in water; and this hath procured it the name of
_Soluble Tartar_. It is also called the _Vegetable Salt_, as being
obtained from vegetables only; and again, _Tartarised Tartar_, because
it consists of the acid and the alkali of Tartar combined together.
Crystals of Tartar combined with alkalis procured from the ashes of
maritime plants, such as Soda, which alkalis resemble the basis of
sea-salt, form likewise a neutral salt, which crystallizes well, and
dissolves easily in water. This salt is another sort of soluble
Tartar. It is called _Saignette's Salt_, from the inventor's name.
Both the Vegetable Salt and Saignette's Salt are gently purgative
soaps, and much used in Medicine.
Tartar likewise dissolves the absorbent earths, as lime, chalk, _&c._
and with them forms neutral salts which are soluble in water[3]. It
even attacks metallic bodies, and when combined with them becomes
soluble. A soluble Tartar for medical use is prepared with Crystals of
Tartar and Iron: the metallic salt thereby produced hath the name of
_Chalybeated Soluble Tartar_. This salt attracts the moisture of the
air, and is one of those which do not crystallize.
[3] See Mr. Duhamel's Essays on this subject in the Memoirs of the
Academy of Sciences.
Public-domain text, read in full here on John Shaqi.
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