ARSENIC (symbol As, atomic weight 75.0), a chemical element, known to
the ancients in the form of its sulphides. Aristotle gave them the name
[Greek: sanoarakae], and Theophrastus mentions them under the name
[Greek: arsenikon]. The oxide known as white arsenic is mentioned by the
Greek alchemist Olympiodorus, who obtained it by roasting arsenic
sulphide. These substances were all known to the later alchemists, who
used minerals containing arsenic in order to give a white colour to
copper. Albertus Magnus was the first to state that arsenic contained a
metal-like substance, although later writers considered it to be a
bastard or semi-metal, and frequently called it _arsenicum rex_. In 1733
G. Brandt showed that white arsenic was the calx of this element, and
after the downfall of the phlogiston theory the views concerning the
composition of white arsenic were identical with those which are now
held, namely that it is an oxide of the element.
Arsenic is found in the uncombined condition in various localities, but
more generally in combination with other metals and sulphur, in the form
of more or less complex sulphides. Native arsenic is usually found as
granular or curvilaminar masses, with a reniform or botryoidal surface.
These masses are of a dull grey colour, owing to surface tarnish; only
on fresh fractures is the colour tin-white with metallic lustre. The
hardness is 3.5 and the specific gravity 5.63-5.73. Crystals of arsenic
belong to the rhombohedral system, and have a perfect cleavage parallel
to the basal plane; natural crystals are, however, of rare occurrence,
and are usually acicular in habit. Native arsenic occurs usually in
metalliferous veins in association with ores of antimony, silver, &c.;
the silver mines of Freiberg in Saxony, St Andreasberg in the Harz, and
Chanarcillo in Chile being well-known localities. Attractive globular
aggregates of well-developed radiating crystals have been found at
Akatani, a village in the province Echizen, in Japan.
Public-domain text, read in full here on John Shaqi.
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