The appearance of the terminals is shown in fig. 18, given by Mrs
Ayrton (_Proc. Inst. Elec. Eng._ 28, p. 400); a, b represent the
terminals when the arc is quiet, and c when it is accompanied by a
hissing sound. The intrinsic brightness of the positive crater does
not increase with an increase in the current; an increased current
produces an increase in the area of the luminous crater, but the
amount of light given out by each unit of area of luminous surface is
unaltered. This indicates that the temperature of the crater is
constant; it is probably that at which carbon volatilizes. W. E.
Wilson (_Proc. Roy. Soc._ 58, p. 174; 60, p. 377) has shown that at
pressures of several atmospheres the intrinsic brightness of the
crater is considerably diminished.
[Illustration: FIG. 18.]
[Illustration: FIG. 19.]
The connexion between V, the potential difference between the
terminals, and l, the length of the arc, is somewhat analogous to that
which holds for the spark discharge. Fröhlich (_Electrotech. Zeit._ 4,
p. 150) gives for this connexion the relation V = m + nl, where m and
n are constants. Mrs Ayrton (_The Electric Arc_, chap. iv.) finds that
both m and n depend upon the current passing between the terminals,
and gives as the relation between V and l, V = [alpha] + [beta]/I +
([gamma] + [delta]/I)l, where [alpha], [beta], [gamma], [delta] are
constants and I the current. The relation between current and
potential difference was made the subject of a series of experiments
by Ayrton (_Electrician_, 1, p. 319; xi. p. 418), some of whose
results are represented in fig. 19. For a quiet arc an increase in
current is accompanied by a fall in potential difference, while for
the hissing arc the potential difference is independent of the
current. The quantities m and n which occur in Fröhlich's equation
have been determined by several experimenters. For carbon electrodes
in air at atmospheric pressure m is about 39 volts, varying somewhat
with the size and purity of the carbons; it is diminished by soaking
the terminals in salt solution. The value of n given by different
observers varies considerably, ranging from .76 to 2 volts when l is
measured in millimetres; it depends upon the current, diminishing as
the current increases. When metallic terminals are used instead of
carbons, the value of m depends upon the nature of the metal, m in
general being larger the higher the temperature at which the metal
volatilizes. Thus v. Lang (_Wied. Ann._ 31, p. 384) found the
following values for m in air at atmospheric pressure:--C = 35; Pt =
27.4; Fe = 25; Ni = 26.18; Cu = 23.86; Ag = 15.23; Zn = 19.86; Cd =
10.28. Lecher (_Wied. Ann._ 33, p. 609) gives Pt = 28, Fe = 20, Ag =
8, while Arons (_Wied. Ann._ 31, p. 384) found for Hg the value 12.8;
in this case the fall of potential along the arc itself was abnormally
small.
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