distinguish himself, as Boyle did, by experimental work in science, his
views exerted only a limited influence amongst his pupils.
Phlogiston theory.
In the times following Boyle's work we find no remarkable outside
development of the theory of elements, but a very important inside one.
Analytical chemistry, or the art of distinguishing different chemical
substances, was rapidly developing, and the necessary foundation for
such a theory was thus laid. We find the discussions about the true
elements disappearing from the text-books, or removed to an
insignificant corner, while the description of observed chemical changes
of different ways of preparing the same substance, as identified by the
same properties, and of the methods for recognizing and distinguishing
the various substances, take their place. The similarity of certain
groups of chemical changes, as, for example, combustion, and the inverse
process, reduction, was observed, and thus led to an attempt to shape
these most general facts into a common theory. In this way the theory of
"phlogiston" was developed by G.E. Stahl, phlogiston being (according to
the usual way of regarding general properties as being due to a
principle or element) the "principle of combustibility," similar to the
"sulphur" of the alchemists. This again must be regarded as quite a
legitimate step justified by the knowledge of the time. For experience
taught that combustibility could be _transferred_ by chemical action,
e.g. from charcoal to litharge, the latter being changed thereby into
combustible metallic lead; and according to Boyle's principle, that only
_bodies_ should be recognized as chemical elements, phlogiston was
considered as a body. From the fact that all leading chemists in the
second half of the 18th century used the phlogiston theory and were not
hindered by it in making their great discoveries, it is evident that a
sufficient amount of truth and usefulness was embodied in this theory.
It states indeed quite correctly the mutual relations between oxidation
and reduction, as we now call these very general processes, and was
erroneous only in regard to one question, which at that time had not
aroused much interest, the question of the change of weight during
chemical processes.
Lavoisier's reform.
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