It was only after Isaac Newton's discovery of universal gravitation that
weight was considered as a property of paramount interest and
importance, and that the question of the changes of weight in chemical
reactions became one worth asking. When in due time this question was
raised, the fact became evident at once, that combustion means not loss
but gain of weight. To be sure of this, it was necessary to know first
the chemical and physical properties of gases, and it was just at the
same time that this knowledge was developed by Priestley, Scheele and
others. Lavoisier was the originator and expounder of the necessary
reform. Oxygen was just discovered at that time, and Lavoisier gathered
evidence from all sides that the theory of phlogiston had to be turned
inside out to fit the new facts.
He realized that the sum total of the weights of all substances
concerned within a chemical change is not altered by the change. This
principle of the "conservation of weight" led at once to a simple and
unmistakable definition of a chemical element. As the weight of a
compound substance is the sum of the weights of its elements, the
compound necessarily weighs more than any of its elements. An element is
therefore a substance which, by being changed into another substance,
invariably increases its weight, and never gives rise to substances of
less weight. By the help of this criterion Lavoisier composed the first
table of chemical elements similar to our modern ones. According to the
knowledge of his time he regarded the alkalis as elements, although he
remarked that they are rather similar to certain oxides, and therefore
may possibly contain oxygen; the truth of this was proved at a later
date by Humphry Davy. But the inconsistency of the reformer, already
referred to, may be observed with Lavoisier. He included "heat and
light" in his list of elements, although he knew that neither of them
had weight, and that neither fitted his definition of an element; this
atavistic survival was subsequently removed from the table of the
elements by Berzelius in the beginning of the 19th century. In this way
the question of what substances are to be regarded as chemical elements
had been settled satisfactorily in a qualitative way, but it is
interesting to realize that the last step in this development, the
theory of Lavoisier, was based on quantitative considerations. Such
considerations became of paramount interest at once, and led to the
concept of the _combining weights of the elements_.
J.B. Richter's work.
Public-domain text, read in full here on John Shaqi.
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