In recent times not only our belief in the absolute exactness of the law
of the conservation of weight has been shaken, but also our belief in
the law of the conservation of the elements. The wonderful substance
radium, whose existence has made us to revise quite a number of old and
established views, seems to be a fulfilment of the old problem of the
alchemists. It is true that by its help lead is not changed into gold,
but radium not only changes itself into another element, helium
(Ramsay), but seems also to cause other elements to change. Work in this
line is of present day origin only and we do not know what new laws will
be found to regulate these most unexpected reactions (see
RADIOACTIVITY). But we realize once more that no law can be regarded as
free from criticism and limitation; in the whole realm of exact sciences
there is no such thing as the Absolute.
Prout's assumption.
Another question regarding the values of atomic weights was raised very
soon after their first establishment. From the somewhat inexact first
determinations William Prout concluded that all atomic weights are
multiples of the atomic weight of hydrogen, thus suggesting all other
elements to be probably made up from condensed hydrogen. Berzelius found
his determinations not at all in accordance with this assumption, and
strongly opposed the arbitrary rounding off of the numbers practised by
the partisans of Prout's hypothesis. His hypothesis remained alive,
although almost every chemist who did _exact_ atomic weight
determinations, especially Stas, contradicted it severely. Even in our
time it seems to have followers, who hope that in some way the existing
experimental differences may disappear. But one of the most important
and best-known relations, that between _hydrogen_ and _oxygen_, is
certainly different from the simple ratio 1 : 16, for it has been
determined by a large number of different investigators and by different
methods to be undoubtedly lower, namely, 1 : 15.87. Therefore, if
Prout's hypothesis contain an element of truth, by the act of
condensation of some simpler substance into the present chemical
elements a change of weight also must have occurred, such that the
weight of the element did not remain exactly the weight of the simpler
substance which changed into it. We have already remarked that such
phenomena are not yet known with certainty, but they cannot be regarded
as utterly impossible.
International table of atomic weights.
Public-domain text, read in full here on John Shaqi.
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