Two other sons of Count Ferencz (d. 1685), Ferencz and Jozsef, founded
the houses of Dotis and Cseklesz (Landschutz) respectively. Of their
descendants, Count MORICZ (1807-1890) of Dotis, Austrian ambassador in
Rome until 1856, became in 1861 a member of the ministry formed by Anton
Schmerling and in 1865 joined the clerical cabinet of Richard Belcredi.
His bitter hostility to Prussia helped to force the government of Vienna
into the war of 1866. His official career closed in 1866, but he
remained one of the leaders of the clerical party.
See also Count Janos Esterhazy, _Description of the Esterhazy Family_
(Hung., Budapest, 1901). (R. N. B.)
ESTERS, in organic chemistry, compounds formed by the condensation of an
alcohol and an acid, with elimination of water; they may also be
considered as derivatives of alcohols, in which the hydroxylic hydrogen
has been replaced by an acid radical, or as acids in which the hydrogen
of the carboxyl group has been replaced by an alkyl or aryl group. In
the case of the polybasic acids, all the hydrogen atoms can be replaced
in this way, and the compounds formed are known as "neutral esters." If,
however, some of the hydrogen of the acid remain undisplaced, then "acid
esters" result. These acid esters retain some of the characteristic
properties of the acids, forming, for example, salts, with basic oxides.
Esters may be prepared by heating the silver salt of an acid with an
alkyl iodide; by heating the alcohols or alcoholates with an acid
chloride; by distilling the anhydrous sodium salt of an acid with a
mixture of the alcohol and concentrated sulphuric acid; or by heating
for some hours on the water bath, a mixture of an acid and an alcohol,
with a small quantity of hydrochloric or sulphuric acids (E. Fischer and
A. Speier, _Ber_., 1896, 28, p. 3252).
The esters of the aliphatic and aromatic acids are colourless neutral
liquids, which are generally insoluble in water, but readily dissolve in
alcohol and ether. Many possess a fragrant odour and are prepared in
large quantities for use as artificial fruit essences. They hydrolyse
readily when boiled with solutions of caustic alkalies or mineral acids,
yielding the constituent acid and alcohol. When heated with ammonia,
they yield acid amides (q.v.). They form unstable addition products with
sodium ethylate or methylate. With the Grignard reagent, they form
addition compounds which on the addition of water yield tertiary
alcohols, except in the case of ethyl formate, where a secondary alcohol
is obtained.
OMgBr OMgBr R'
/ / \
R.CO2C2H5 --> R.C--OC2H5 --> R.C--R' --> R'--C.OH.
\ \ /
R' R' R'
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