ERBIUM (symbol, Er; atomic weight, 165-166), one of the metals of the
rare earths. The first of the rare earth minerals was discovered in 1794
by J. Gadolin and was named gadolinite from its discoverer. In 1797
Ekeberg showed that gadolinite contained another rare earth, which was
given the name yttria. Yttria is an exceedingly complex mixture, which
has been decomposed, yielding as an intermediate product terbia. This
latter substance in its turn has been split by J.L. Soret, P.T. Cleve,
Lecoq de Boisbaudran and others into erbia, holmia, thulia and
dysprosia, but it is still doubtful whether any one of these four
splitting products is a single substance. The rare earth metals are
found in the minerals gadolinite, samarskite, fergusonite, euxenite and
cerite. They are separated from the minerals by converting them into
oxalates, which by ignition give the corresponding oxides. The oxides
are then converted into double sulphates which are separated from each
other by repeated fractional crystallization or by fractional
precipitation with ammonia or some other base. Erbium forms
rose-coloured salts and a rose-coloured oxide. The oxide dissolves
slowly in acids; it is not reduced by hydrogen and is infusible. The
salts show a characteristic absorption spectrum.
See J.F. Bahr and R. Bunsen (_Ann._, 1866, 137, p. 1); A. v. Welsbach
(_Monats._, 1883, 4, p. 641; 1884, 5, p. 508; 1885, 6, p. 477); P.T.
Cleve (_Comptes rendus_, 1879, 89, p. 478; 1880, 91, pp. 328, 381;
1882, 95, p. 1225; _Bull. de la soc. chim._, 1874, 21, p. 196; 1883,
39, p. 287); C. Marignac (_Ann. Chim. phys._, 1849 [3] 27, p. 226); B.
Brauner (_Monats._, 1882, 3, p. 13); W. Crookes (_Proc. Roy. Soc._,
1886, 40, p. 502); Lecoq de Boisbaudran (_Comptes rendus_, 1886, 102,
p. 1005); A. Bettendorf (_Ann._, 1892, 270, p. 376); M. Muthmann
(_Ber._, 1898, 31, p. 1718; 1900, 33, p. 42); G. Kruss (_Zeit. f.
anorg. Chem._, 1893, 3, p. 108).
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