between Fundi and Formiae. In 188 B.C., with Fundi, it received the full
citizenship, and, like it, was to a certain extent under the control of
a _praefectus_ sent from Rome, though it retained its three aediles.
Mamurra was a native of Formia. Cicero possessed a favourite villa here,
and was murdered in its vicinity in 43 B.C., but neither the villa nor
the tomb can be identified with any certainty. It was devastated by
Sextus Pompeius, and became a colony, with _duoviri_ as chief
magistrates, under Hadrian. Portus Caietae (the modern Gaeta) was
dependent upon it.
See T. Ashby, "Dessins inedits de Carlo Labruzzi," in _Melanges de
l'ecole francaise de Rome_ (1903), 410 seq. (T. As.)
FORMIC ACID, H2CO2 or H.COOH, the first member of the series of
aliphatic monobasic acids of the general formula CnH_(2n)O2. It is
distinguished from the other members of the series by certain
characteristic properties; for example, it shows an aldehydic character
in reducing silver salts to metallic silver, and it does not form an
acid chloride or an acid anhydride. Its nitrile (prussic acid) has an
acid character, a property not possessed by the nitriles of the other
members of the series; and, by the abstraction of the elements of water
from the acid, carbon monoxide is produced, a reaction which finds no
parallel in the higher members of the series. Finally, formic acid is,
as shown by the determination of its affinity constant, a much stronger
acid than the other acids of the series. It occurs naturally in red ants
(Lat. _formica_), in stinging nettles, in some mineral waters, in animal
secretions and in muscle. It may be prepared artificially by the
oxidation of methyl alcohol and of formaldehyde; by the rapid heating of
oxalic acid (J. Gay-Lussac, _Ann. chim. phys._, 1831 [2] 46, p. 218),
but best by heating oxalic acid with glycerin, at a temperature of
100-110 deg. C. (M. Berthelot, _Ann._, 1856, 98, p. 139). In this
reaction a glycerol ester is formed as an intermediate product, and
undergoes decomposition by the water which is also produced at the same
time.
C3H5(OH)3 + H2C2O4 = C3H5(OH)2.OCHO+CO2 + H2O
C3H5(OH)2O.CHO + H2O = C3H5(OH)3 + H2CO2.
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