In applied chemistry Frankland's great work was in connexion with
water-supply. Appointed a member of the second royal commission on the
pollution of rivers in 1868, he was provided by the government with a
completely-equipped laboratory, in which, for a period of six years, he
carried on the inquiries necessary for the purposes of that body, and
was thus the means of bringing to light an enormous amount of valuable
information respecting the contamination of rivers by sewage,
trade-refuse, &c., and the purification of water for domestic use. In
1865, when he succeeded A. W. von Hofmann at the School of Mines, he
undertook the duty of making monthly reports to the registrar-general on
the character of the water supplied to London, and these he continued
down to the end of his life. At one time he was an unsparing critic of
its quality, but in later years he became strongly convinced of its
general excellence and wholesomeness. His analyses were both chemical
and bacteriological, and his dissatisfaction with the processes in vogue
for the former at the time of his appointment caused him to spend two
years in devising new and more accurate methods. In 1859 he passed a
night on the very top of Mont Blanc in company with John Tyndall. One of
the purposes of the expedition was to discover whether the rate of
combustion of a candle varies with the density of the atmosphere in
which it is burnt, a question which was answered in the negative. Other
observations made by Frankland at the time formed the starting-point of
a series of experiments which yielded far-reaching results. He noticed
that at the summit the candle gave a very poor light, and was thereby
led to investigate the effect produced on luminous flames by varying the
pressure of the atmosphere in which they are burning. He found that
pressure increases luminosity, so that hydrogen, for example, the flame
of which in normal circumstances gives no light, burns with a luminous
flame under a pressure of ten or twenty atmospheres, and the inference
he drew was that the presence of solid particles is not the only factor
that determines the light-giving power of a flame. Further, he showed
that the spectrum of a dense ignited gas resembles that of an
incandescent liquid or solid, and he traced a gradual change in the
spectrum of an incandescent gas under increasing pressure, the sharp
lines observable when it is extremely attenuated broadening out to
nebulous bands as the pressure rises, till they merge in the continuous
spectrum as the gas approaches a density comparable with that of the
liquid state. An application of these results to solar physics in
conjunction with Sir Norman Lockyer led to the view that at least the
external layers of the sun cannot consist of matter in the liquid or
solid forms, but must be composed of gases or vapours. Frankland and
Lockyer were also the discoverers of helium. In 1868 they noticed in the
solar spectrum a bright yellow line which did not correspond to any
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