atmosphere, absorb water, or become hydrous, and are then usually more
prone to further change. Hence the rocks of which they form part
become disintegrated.
Besides the reactions here enumerated, a considerable amount of decay
may be observed as the result of the presence of sulphuric and nitric
acid in the air, especially in that of large towns and manufacturing
districts, where much coal is consumed. Metallic surfaces, as well as
various kinds of stone, are there corroded, while the mortar of walls
may often be observed to be slowly swelling out and dropping off,
owing to the conversion of the lime into sulphate. Great injury is
likewise done from a similar cause to marble monuments in exposed
graveyards.
The general result of the disintegrating action of the air and of
rain, including also that of plants and animals, to be noticed in the
sequel, is denoted by the term "weathering." The amount of decay
depends partly on conditions of climate, especially the range of
temperature, the abundance of moisture, height above the sea and
exposure to prevalent winds. Many rocks liable to be saturated with
rain and rapidly dried under a warm sun are apt to disintegrate at the
surface with comparative rapidity. The nature and progress of the
weathering are mainly governed by the composition and texture of the
rocks exposed to it. Rocks composed of particles liable to little
chemical change from the influence of moisture are best fitted to
resist weathering, provided they possess sufficient cohesion to
withstand the mechanical processes of disintegration. Siliceous
sandstones are excellent examples of this permanence. Consisting
wholly or mainly of the durable mineral quartz, they are sometimes
able so to withstand decay that buildings made of them still retain,
after the lapse of centuries, the chisel-marks of the builders. Some
rocks, which yield with comparative rapidity to the chemical attacks
of moisture, may show little or no mark of disintegration on their
surface. This is particularly the case with certain calcareous rocks.
Limestone when pure is wholly soluble in acidulated water. Rain
falling on such a rock removes some of it in solution, and will
continue to do so until the whole is dissolved away. But where a
limestone is full of impurities, a weathered crust of more or less
insoluble particles remains after the solution of the calcareous part
of the stone. Hence the relative purity of limestones may be roughly
determined by examining their weathered surfaces, where, if they
contain much sand, the grains will be seen projecting from the
calcareous matrix, and where, should the rock be very ferruginous, the
yellow hydrous peroxide, or ochre, will be found as a powdery crust.
In limestones containing abundant encrinites, shells, or other organic
remains, the weathered surface commonly presents the fossils standing
out in relief.
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