Encyclopaedia Britannica, 11th Edition, "Groups, Theory of" to "Gwyniad": Volume 12, Slice 6Various
Science
Encyclopaedia Britannica, 11th Edition, "Groups, Theory of" to "Gwyniad": Volume 12, Slice 6
Various
Encyclopedias and dictionaries
Chips or turnings of the heartwood of _G. officinale_ (_guaiaci lignum_)
are employed in the preparation of the _liquor sarsae compositus
concentratus_ of British pharmacy. They may be recognized by being
either yellow of greenish-brown in colour, and by turning bluish-green
when treated with nitric acid, or when heated with corrosive sublimate,
and green with solution of chloride of lime. They are occasionally
adulterated with boxwood shavings. Lignum vitae is imported chiefly from
St Domingo, the Bahamas and Jamaica.
The bark was formerly used in medicine; it contains much calcium
oxalate, and yields on incineration 23% of ash. Guaiacum resin, the
_guaiaci resina_ of pharmacopoeias, is obtained from the wood as an
exudation from natural fissures or from incisions; by heating billets
about 3 ft. in length, bored to permit of the outflow of the resin; or
by boiling chips and raspings in water to which salt has been added to
raise the temperature of ebullition. It occurs in rounded or oval
tears, commonly coated with a greyish-green dust, and supposed to be
the produce of _G. sanctum_, or in large brownish or greenish-brown
masses, translucent at the edges; fuses at 85 deg. C.; is brittle, and
has a vitreous fracture, and a slightly balsamic odour, increased by
pulverization and by heat; and is at first tasteless when chewed, but
produces subsequently a sense of heat in the throat. It is readily
soluble in alcohol, ether, chloroform, creosote, oil of cloves and
solutions of caustic alkalies; and its solution gives a blue colour
with gluten, raw potato parings and the roots of horse-radish, carrot
and various other plants. The alcoholic tincture becomes green with
sodium hypochlorite, and with nitric acid turns in succession green,
blue and brown. With glycerin it gives a clear solution, and with
nitrous ether a bluish-green gelatinous mass. It is blued by various
oxidizing agents, e.g. ozone, and, as Schonbein discovered, by the
juice of certain fungi. The chief constituents are three distinct
resins, _guaiaconic acid_, C19H20O5 (70%), _guaiac acid_, which is
closely allied to benzoic acid, and _guaiaretic acid_. Like all
resins, these are insoluble in water, soluble in alkalies, but
precipitated on neutralization of the alkaline solution.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account