alcohol, and finally fractionated under reduced pressure. The free base
is a colourless, odourless, crystalline solid, melting at about 30° C.,
and boiling at 58° C. (under a pressure of 22 mm.). It deliquesces and
oxidizes on exposure, inflames in dry chlorine and is reduced to ammonia
by zinc dust. Its aqueous solution is strongly alkaline, and with acids
it forms well-defined stable salts. E. Ebler and E. Schott (_J. pr.
Chem._, 1908, 78, p. 289) regard it as acting with the formula NH2·OH
towards bases, and as NH3:O towards acids, the salts in the latter case
being of the oxonium type. It is a strong reducing agent, giving a
precipitate of cuprous oxide from alkaline copper solutions at ordinary
temperature, converting mercuric chloride to mercurous chloride, and
precipitating metallic silver from solutions of silver salts. With
aldehydes and ketones it forms oximes (q.v.). W. R. Dunstan (_Jour.
Chem. Soc._, 1899, 75, p. 792) found that the addition of methyl iodide
to a methyl alcohol solution of hydroxylamine resulted in the formation
of trimethyloxamine, N(CH3)3O.
Many substituted hydroxylamines are known, substitution taking place
either in the [alpha] or [beta] position
[beta] [alpha]
(NH2 · OH^).
[beta]-phenylhydroxyl-amine, C6H5NH·OH·, is obtained in the reduction
of nitrobenzene in neutral solution (e.g. by the action of the
aluminium-mercury couple and water), but better, according to C.
Goldschmidt (_Ber._, 1896, 29, p. 2307) by dissolving nitrobenzene in
ten times its weight of ether containing a few cubic centimetres of
water, and heating with excess of zinc dust and anhydrous calcium
chloride for three hours on a water bath. It also appears as an
intermediate product in the electrolytic reduction of nitrobenzene in
sulphuric acid solution. By gentle oxidation it yields nitrosobenzene.
Derivatives of the type R2N·OH result in the action of the Grignard
reagent on amyl nitrite. Dihydroxy-ammonia or nitroxyl, NH(OH)2, a
very unstable and highly reactive substance, has been especially
studied by A. Angeli (see A. W. Stewart, _Recent Advances in Physical
and Inorganic Chemistry_, 1909).
HYDROZOA, one of the most widely spread and prolific groups of aquatic
animals. They are for the most part marine in habitat, but a familiar
fresh-water form is the common _Hydra_ of ponds and ditches, which gives
origin to the name of the class. The Hydrozoa comprise the hydroids, so
abundant on all shores, most of which resemble vegetable organisms to
the unassisted eye; the hydrocorallines, which, as their name implies,
have a massive stony skeleton and resemble corals; the jelly-fishes so
called; and the Siphonophora, of which the species best known by repute
is the so-called "Portuguese man-of-war" (_Physalia_), dreaded by
sailors on account of its terrible stinging powers.
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