Kaolin is a hydrous aluminium silicate, having the formula H4Al2Si2O9,
or Al2Si2O7.2H2O, but in common clay this silicate is largely mixed with
impurities. Certain clays contain pearly white hexagonal scales, usually
microscopic, referable to the monoclinic system, and having the chemical
composition of kaolin. This crystalline substance was termed kaolinite
by S. W. Johnson and J. M. Blake in 1867, and it is now regarded as the
basis of pure clay. The kaolinite of Amlwch in Anglesey has been studied
by Allan Dick. The origin of kaolin may be traced to the alteration of
certain aluminous silicates like feldspar, scapolite, beryl and topaz;
but all large deposits of china-clay are due to the decomposition of
feldspar, generally in granite, but sometimes in gneiss, pitchstone, &c.
The turbidity of many feldspars is the result of partial
"kaolinization," or alteration to kaolin. The china-clay rocks of
Cornwall and Devon are granites in which the orthoclase has become
kaolinized. These rocks are sometimes known as carclazite, a name
proposed by J. H. Collins from a typical locality, the Carclaze mine,
near St Austell. It has often been supposed that the alteration of the
granite has been effected mainly by meteoric agencies, the carbonic acid
having decomposed the alkaline silicate of the feldspar, whilst the
aluminous silicate assumes a hydrated condition and forms kaolin. In
many cases, however, it seems likely that the change has been effected
by subterranean agencies, probably by heated vapours carrying fluorine
and boron, since minerals containing these elements, like tourmaline,
often occur in association with the china-clay. According to F. H.
Butler the kaolinization of the west of England granite may have been
effected by a solution of carbonic acid at a high temperature, acting
from below.
The china-stone, or petuntse, is a granitic rock which still retains
much of the unaltered feldspar, on which its fusibility depends. In
order to prepare kaolin for the market, the china-clay rock is broken
up, and the clay washed out by means of water. The liquid containing
the clay in mechanical suspension is run into channels called "drags"
where the coarser impurities subside, and whence it passes to another
set of channels known as "micas," where the finer materials settle down.
Thus purified, the clay-water is led into a series of pits or tanks, in
which the finely divided clay is slowly deposited; and, after acquiring
sufficient consistency, it is transferred to the drying-house, or "dry,"
heated by flues, where the moisture is expelled, and the kaolin obtained
as a soft white earthy substance. The clay has extensive application in
the arts, being used not only in ceramic manufacture but in
paper-making, bleaching and various chemical industries.
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