_Lithium hydride_, LiH, obtained by heating the metal in a current of
hydrogen at a red heat, or by heating the metal with ethylene to 700°
C. (M. Guntz, _Comptes rendus_, 1896, 122, p. 244; 123, p. 1273), is a
white solid which inflames when heated in chlorine. With alcohol it
forms lithium ethylate, LiOC2H5, with liberation of hydrogen. _Lithium
oxide_, Li2O, is obtained by burning the metal in oxygen, or by
ignition of the nitrate. It is a white powder which readily dissolves
in water to form the _hydroxide_, LiOH, which is also obtained by
boiling the carbonate with milk of lime. It forms a white caustic
mass, resembling sodium hydroxide in appearance. It absorbs carbon
dioxide, but is not deliquescent. _Lithium chloride_ LiCl, prepared by
heating the metal in chlorine, or by dissolving the oxide or carbonate
in hydrochloric acid, is exceedingly deliquescent, melts below a red
heat, and is very soluble in alcohol. _Lithium carbonate_, Li2CO3,
obtained as a white amorphous precipitate by adding sodium carbonate
to a solution of lithium chloride, is sparingly soluble in water.
_Lithium phosphate_, Li3PO4, obtained by the addition of sodium
phosphate to a soluble lithium salt in the presence of sodium
hydroxide, is almost insoluble in water. _Lithium ammonium_, LiNH3, is
obtained by passing ammonia gas over lithium, the product being heated
to 70° C. in order to expel any excess of ammonia. It turns brown-red
on exposure to air, and is inflammable. It is decomposed by water
evolving hydrogen, and when heated _in vacuo_ at 50°-60° C. it gives
lithium and ammonia. With ammonia solution it gives hydrogen and
_lithiamide_, LiNH2 (H. Moissan, _ibid._, 1898, 127, p. 685). _Lithium
carbide_, Li2C2, obtained by heating lithium carbonate and carbon in
the electric furnace, forms a transparent crystalline mass of specific
gravity 1.65, and is readily decomposed by cold water giving acetylene
(H. Moissan, _ibid._, 1896, 122, p. 362).
Lithium is detected by the faint yellow line of wave-length 6104, and
the bright red line of wave-length 6708, shown in its flame spectrum.
It may be distinguished from sodium and potassium by the sparing
solubility of its carbonate and phosphate. The atomic weight of
lithium was determined by J. S. Stas from the analysis of the
chloride, and also by conversion of the chloride into the nitrate, the
value obtained being 7.03 (O = 16).
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