The crystals are isomorphous with mispickel (q.v.), but only rarely are
they distinctly developed and simple (fig.). Usually they are twinned on
a prism plane, M, producing pentagonal stellate groups of five crystals;
twinning on the plain g, in which the crystals intercross at angles of
nearly 60°, is less common. This frequent twinning gives rise to
characteristic forms, with many re-entrant angles, to which the names
"spear pyrites" and "cockscomb pyrites" are applied. The commonest state
of aggregation is that of radially arranged fibres, the external surface
of the mass being globular, nodular or stalactitic in form.
Apart from crystalline form, the external characters of marcasite are
very similar to those of pyrites, and when distinct crystals are not
available the two species cannot always be easily distinguished. The
colour is usually pale bronze-yellow, often rather lighter than that of
pyrites; on freshly fractured surfaces of pure marcasite the colour is
tin-white, but this rapidly tarnishes on exposure to air. The lustre is
metallic and brilliant. The streak is greyish or brownish-black. The
hardness (6-6½) is the same as that of pyrites, and the specific gravity
(4.8-4.9) as a rule rather less. Arsenical varieties of marcasite,
containing up to 5% of arsenic, are known as lonchidite and kyrosite.
Marcasite readily oxidizes on exposure to moist air, with the
production of sulphuric acid and a white fibrous efflorescence of
ferrous sulphate, and in course of time specimens in collections often
became completely disintegrated. In nature it is frequently altered to
limonite with the separation of native sulphur. Marcasite is thus the
less stable of the two modifications of iron disulphide. Many
experiments have been made with a view to determining the difference
in chemical constitution of marcasite and pyrites, but with no very
definite results. It is a noteworthy fact that whilst pyrites has been
prepared artificially, marcasite has not.
Marcasite occurs under the same conditions as pyrites, but is much
less common. Whilst pyrites is found abundantly in the older
crystalline rocks and slates, marcasite is more abundant in clays, and
has often been formed as a concretion around organic remains. It is
abundant, for example, in the plastic clay of the Brown Coal formation
at Littmitz, near Carlsbad, in Bohemia, at which place it has been
extensively mined for the manufacture of sulphur and ferrous sulphate.
In the Chalk of the south-east of England nodules of marcasite with a
fibrous radiated structure are abundant, and in the Chalk Marl between
Dover and Folkestone fine twinned groups of "spear pyrites" are
common. The mineral is also met with in metalliferous veins, though
much less frequently than pyrites; for example the "cockscomb pyrites"
of the lead mines of Derbyshire and Cumberland. (L. J. S.)
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