Essays: Scientific, Political, & Speculative; Vol. 2 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.Spencer, Herbert
Philosophy
Essays: Scientific, Political, & Speculative; Vol. 2 of 3: Library Edition (1891), Containing Seven Essays not before Republished, and Various other Additions.
Spencer, Herbert
Philosophy; Political science; Science
This interpretation of the facts of thermo-electricity will probably
be met by the objection that there are, in some cases, thermo-electric
currents developed between masses of metal of the same kind, and even
between different parts of the same mass. It may be urged that, if
unlikeness between the rates of vibration of molecules in contact
{175} is the cause of these electric disturbances; then, heat ought
not to produce any electric disturbances when the molecules are of the
same kind; since heat does not change the periodic times of molecular
vibrations. This objection, which seems at first sight a serious one,
introduces us to a confirmation. For where the masses of molecules
are homogeneous in all other respects, difference of temperature
does _not_ generate any thermo-electric current. The junction of hot
with cold mercury sets up no electric excitement. In all cases where
thermo-electricity is generated between metals of the same kind, there
is evidence of heterogeneity in their molecular structures—either one
has been hammered and the other not, or one is annealed and the other
unannealed. And where the current is between different parts of the
same mass, there are differences in the crystalline states of the
parts, or differences between the ways in which the parts have cooled
after being cast. That is to say, there is proof that the molecules in
the two masses, or in different parts of the same mass, are in unlike
relations to their neighbours—are in unlike states of tension. Now,
however true it may be that molecules of the same kind vibrate at the
same rate, whatever may be their temperature, it is obviously true so
long only as their motions are not modified by restraining forces. If
molecules of the same kind are in one mass arranged into that state
which constitutes crystallization, while in another mass they are not
thus bound together; or if in the one their molecular relations have
been modified by hammering, and in the other not; the differences
in the restraints under which they respectively vibrate will affect
their rates of vibration. And if their rates of vibration are rendered
unequal, then the alleged cause of electrical disturbance comes into
existence.
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