Every-day Science: Volume 6. The Conquest of NatureWilliams, Henry Smith
Science
Every-day Science: Volume 6. The Conquest of Nature
Williams, Henry Smith
Industrial arts; Machinery
But all this, of course, leaves quite untouched the question of the
origin of the electrons themselves. That these go hurtling from one
plate or pole of the battery to the other, along the wire, we can
understand at least as a working theory; that, furthermore, the
electrons have their origin either in the metal plates or in the liquid
that connects them, seems equally obvious; but how shall we account for
their development? It is here that the chemist with his atomic theory
of matter comes to our aid. He assures us that all matter consists
in the last analysis of excessively minute particles, and that these
particles are perpetually in motion. They unite with one another to
form so-called molecules, but they are perpetually breaking away from
such unions, even though they re-establish them again. Such activities
of the atoms take place even in solids, but they are greatly enhanced
when any substance passes from the solid into the liquid state.
When, for example, a lump of salt is dissolved in water, the atoms of
sodium and of chlorine which joined together make up the molecules of
salt are held in much looser bondage than they were while the salt
was in a dry or crystalline form. Could we magnify the infinitesimal
particles sufficiently to make them visible we should probably see
large numbers of the molecules being dissociated, the liberated atoms
moving about freely for an instant and then reuniting with other atoms.
Thus at any given instant our solution of salt would contain numerous
free _atoms_ of sodium and of chlorine, although we are justified in
thinking of this substance as a whole as composed of sodium-chlorine
_molecules_. It is only by thus visualizing the activity of the atoms
in a solution that we are able to provide even a thinkable hypothesis
as to the development of electricity in the voltaic cell.
What puts us on the track of the explanation we are seeking is the
fact that the diverse atoms are known to have different electrical
properties. In our voltaic cell, for example, sodium atoms would
collect at one pole and chlorine atoms at the other. Humphry Davy
discovered this fact in the early days of electro-chemistry, just about
a century ago. He spoke of the sodium atom as electro-positive, and
of the chlorine atom as electro-negative, and he attempted to explain
all chemical affinity as merely due to the mutual attraction between
positively and negatively electrified atoms. The modern theorist goes
one step farther, and explains the negative properties of the chlorine
atom by assuming the presence of one negative electron or electricity
in excess of the neutralizing charge. The assumption is, that the
sodium atom has lost this negative electron and thus has become
positively electrified. The chlorine atom, harboring the fugitive
electron, becomes negatively electrified. Hence the two atoms are
attracted toward opposite poles of the cell.
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