Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
503. It is very evident, that when the width of the decomposing conductor
varies, as is always the case when mere wires or plates, as poles, are
dipped into or are surrounded by solution, no constant expression can be
given as to the action upon a single particle placed in the course of the
current, nor any conclusion of use, relative to the supposed attractive or
repulsive force of the poles, be drawn. The force will vary as the distance
from the pole varies; as the particle is directly between the poles, or
more or less on one side; and even as it is nearer to or further from the
sides of the containing vessels, or as the shape of the vessel itself
varies; and, in fact, by making variations in the form of the arrangement,
the force upon any single particle may be made to increase, or diminish, or
remain constant, whilst the distance between the particle and the pole
shall remain the same; or the force may be made to increase, or diminish,
or remain constant, either as the distance increases or as it diminishes.
504. From numerous experiments, I am led to believe the following general
expression to be correct; but I purpose examining it much further, and
would therefore wish not to be considered at present as pledged to its
accuracy. The _sum of chemical decomposition is constant_ for any section
taken across a decomposing conductor, uniform in its nature, at whatever
distance the poles may be from each other or from the section; or however
that section may intersect the currents, whether directly across them, or
so oblique as to reach almost from pole to pole, or whether it be plane, or
curved, or irregular in the utmost degree; provided the current of
electricity be retained constant in quantity (377.), and that the section
passes through every part of the current through the decomposing conductor.
505. I have reason to believe that the statement might be made still more
general, and expressed thus: That _for a constant quantity of electricity,
whatever the decomposing conductor may be, whether water, saline solutions,
acids, fused bodies, &c., the amount of electro-chemical action is also a
constant quantity, i.e. would always be equivalent to a standard chemical
effect founded upon ordinary chemical affinity_. I have this investigation
in hand, with several others, and shall be prepared to give it in the next
series but one of these Researches.
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