Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
536. Then it explains why, in numerous cases, the elements or evolved
substances are not _retained_ by the poles; and this is no small difficulty
in those theories which refer the decomposing effect directly to the
attractive power of the poles. If, in accordance with the usual theory, a
piece of platina be supposed to have sufficient power to attract a particle
of hydrogen from the particle of oxygen with which it was the instant
before combined, there seems no sufficient reason, nor any fact, except
those to be explained, which show why it should not, according to analogy
with all ordinary attractive forces, as those of gravitation, magnetism,
cohesion, chemical affinity, &c. _retain_ that particle which it had just
before taken from a distance and from previous combination. Yet it does not
do so, but allows it to escape freely. Nor does this depend upon its
assuming the gaseous state, for acids and alkalies, &c. are left equally at
liberty to diffuse themselves through the fluid surrounding the pole, and
show no particular tendency to combine with or adhere to the latter. And
though there are plenty of cases where combination with the pole does take
place, they do not at all explain the instances of non-combination, and do
not therefore in their particular action reveal the general principle of
decomposition.
537. But in the theory that I have just given, the effect appears to be a
natural consequence of the action: the evolved substances are _expelled_
from the decomposing mass (518. 519.), not _drawn out by an attraction_
which ceases to act on one particle without any assignable reason, while it
continues to act on another of the same kind: and whether the poles be
metal, water, or air, still the substances are evolved, and are sometimes
set free, whilst at others they unite to the matter of the poles, according
to the chemical nature of the latter, i.e. their chemical relation to those
particles which are leaving the substance under operation.
538. The theory accounts for the _transfer of elements_ in a manner which
seems to me at present to leave nothing unexplained; and it was, indeed,
the phenomena of transfer in the numerous cases of decomposition of bodies
rendered fluid by heat (380. 402.), which, in conjunction with the
experiments in air, led to its construction. Such cases as the former where
binary compounds of easy decomposability are acted upon, are perhaps the
best to illustrate the theory.
539. Chloride of lead, for instance, fused in a bent tube (400.), and
decomposed by platina wires, evolves lead, passing to what is usually
called the negative pole, and chlorine, which being evolved at the positive
pole, is in part set free, and in part combines with the platina. The
chloride of platina formed, being soluble in the chloride of lead, is
subject to decomposition, and the platina itself is gradually transferred
across the decomposing matter, and found with the lead at the negative
pole.
Public-domain text, read in full here on John Shaqi.
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