Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
569. Several platina plates were prepared (fig. 57.). They were nearly half
an inch wide, and two inches and a half long: some were 1/200dth of an
inch, others not more than 1/600dth, whilst some were as much as 1/70th of
an inch in thickness. Each had a piece of platina wire, about seven inches
long, soldered to it by pure gold. Then a number of glass tubes were
prepared: they were about nine or ten inches in length, 5/8ths of an inch
in internal diameter, were sealed hermetically at one extremity, and were
graduated. Into these tubes was put a mixture of two volumes of hydrogen
and one of oxygen, at the water pneumatic trough, and when one of the
plates described had been connected with the positive or negative pole of
the voltaic battery for a given time, or had been otherwise prepared, it
was introduced through the water into the gas within the tube; the whole
set aside in a test-glass (fig. 58.), and left for a longer or shorter
period, that the action might be observed.
570. The following result may be given as an illustration of the phenomenon
to be investigated. Diluted sulphuric acid, of the specific gravity 1.336,
was put into a glass jar, in which was placed also a large platina plate,
connected with the negative end of a voltaic battery of forty pairs of
four-inch plates, with double coppers, and moderately charged. One of the
plates above described (569.) was then connected with the positive
extremity, and immersed in the same jar of acid for five minutes, after
which it was separated from the battery, washed in distilled water, and
introduced through the water of the pneumatic trough into a tube containing
the mixture of oxygen and hydrogen (569.). The volume of gases immediately
began to lessen, the diminution proceeding more and more rapidly until
about 3/4ths of the mixture had disappeared. The upper end of the tube
became quite warm, the plate itself so hot that the water boiled as it rose
over it; and in less than a minute a cubical inch and a half of the gases
were gone, having been combined by the power of the platina, and converted
into water.
571. This extraordinary influence acquired by the platina at the positive
pole of the pile, is exerted far more readily and effectively on oxygen and
hydrogen than on any other mixture of gases that I have tried. One volume
of nitrous gas was mixed with a volume of hydrogen, and introduced into a
tube with a plate which had been made positive in the dilute sulphuric acid
for four minutes (570.). There was no sensible action in an hour: being
left for thirty-six hours, there was a diminution of about one-eighth of
the whole volume. Action had taken place, but it had been very feeble.
Public-domain text, read in full here on John Shaqi.
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