Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
579. The effect of a solution of caustic potassa in preserving the platina
plates was tried in a similar manner. After being retained in such a
solution for forty hours, they acted exceedingly well on oxygen and
hydrogen, and one caused such rapid condensation of the gases, that the
plate became much heated, and I expected the temperature would have risen
to ignition.
580. When similarly prepared plates (569.) had been put into distilled
water for forty hours, and then introduced into mixed oxygen and hydrogen,
they were found to act but very slowly and feebly as compared with those
which had been preserved in acid or alkali. When, however, the quantity of
water was but small, the power was very little impaired after three or four
days. As the water had been retained in a wooden vessel, portions of it
were redistilled in glass, and this was found to preserve prepared plates
for a great length of time. Prepared plates were put into tubes with this
water and closed up; some of them, taken out at the end of twenty-four
days, were found very active on mixed oxygen and hydrogen; others, which
were left in the water for fifty-three days, were still found to cause the
combination of the gases. The tubes had been closed only by corks.
581. The act of combination always seemed to diminish, or apparently
exhaust, the power of the platina plate. It is true, that in most, if not
all instances, the combination of the gases, at first insensible, gradually
increased in rapidity, and sometimes reached to explosion; but when the
latter did not happen, the rapidity of combination diminished; and although
fresh portions of gas were introduced into the tubes, the combination went
on more and more slowly, and at last ceased altogether. The first effect of
an increase in the rapidity of combination depended in part upon the water
flowing off from the platina plate, and allowing a better contact with the
gas, and in part upon the heat evolved during the progress of the
combination (630.). But notwithstanding the effect of these causes,
diminution, and at last cessation of the power, always occurred. It must
not, however, be unnoticed, that the purer the gases subjected to the
action of the plate, the longer was its combining power retained. With the
mixture evolved at the poles of the voltaic pile, in pure dilute sulphuric
acid, it continued longest; and with oxygen and hydrogen, of perfect
purity, it probably would not be diminished at all.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account