Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
617. It may be observed of this action, that, with regard to platina, it
cannot be due to any peculiar, temporary condition, either of an electric
or of any other nature: the activity of plates rendered either positive or
negative by the pole, or cleaned with such different substances as acids,
alkalies, or water; charcoal, emery, ashes, or glass; or merely heated, is
sufficient to negative such an opinion. Neither does it depend upon the
spongy and porous, or upon the compact and burnished, or upon the massive
or the attenuated state of the metal, for in any of these states it may be
rendered effective, or its action may be taken away. The only essential
condition appears to be a _perfectly clean_ and _metallic surface_, for
whenever that is present the platina acts, whatever its form and condition
in other respects may be; and though variations in the latter points will
very much affect the rapidity, and therefore the visible appearances and
secondary effects, of the action, i.e. the ignition of the metal and the
inflammation of the gases, they, even in their most favourable state,
cannot produce any effect unless the condition of a clean, pure, metallic
surface be also fulfilled.
618. The effect is evidently produced by most, if not all, solid bodies,
weakly perhaps by many of them, but rising to a high degree in platina.
Dulong and Thenard have very philosophically extended our knowledge of the
property to its possession by all the metals, and by earths, glass, stones,
&c. (611.); and every idea of its being a known and recognised electric
action is in this way removed.
619. All the phenomena connected with this subject press upon my mind the
conviction that the effects in question are entirely incidental and of a
secondary nature; that they are dependent upon the _natural conditions_ of
gaseous elasticity, combined with the exertion of that attractive force
possessed by many bodies, especially those which are solid, in an eminent
degree, and probably belonging to all; by which they are drawn into
association more or less close, without at the same time undergoing
chemical combination, though often assuming the condition of adhesion; and
which occasionally leads, under very favourable circumstances, as in the
present instance, to the combination of bodies simultaneously subjected to
this attraction. I am prepared myself to admit (and probably many others
are of the same opinion), both with respect to the attraction of
aggregation and of chemical affinity, that the sphere of action of
particles extends beyond those other particles with which they are
immediately and evidently in union (523.), and in many cases produces
effects rising into considerable importance: and I think that this kind of
attraction is a determining cause of Doebereiner's effect, and of the many
others of a similar nature.
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