Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
676. It must not be forgotten, however, that much of this difficulty, and
perhaps the whole, may depend upon the absence of conducting power, which,
preventing the transmission of the current, prevents of course the effects
due to it. All known compounds being non-conductors when solid, but
conductors when liquid, are decomposed, with _perhaps_ the single exception
at present known of periodide of mercury (679. 691.)[A]; and even water
itself, which so easily yields up its elements when the current passes, if
rendered quite pure, scarcely suffers change, because it then becomes a
very bad conductor.
[A] See now, 1340, 1341.--_Dec. 1838._
677. If it should hereafter be proved that the want of decomposition in
those cases where, from chemical considerations, it might be so strongly
expected (669, 672. 674.), is due to the absence or deficiency of
conducting power, it would also at the same time be proved that
decomposition _depends_ upon conduction, and not the latter upon the former
(413.); and in water this seems to be very nearly decided. On the other
hand, the conclusion is almost irresistible, that in electrolytes the power
of transmitting the electricity across the substance is _dependent_ upon
their capability of suffering decomposition; taking place only whilst they
are decomposing, and being proportionate to the quantity of elements
separated (821.). I may not, however, stop to discuss this point
experimentally at present.
678. When a compound contains such elements as are known to pass towards
the opposite extremities of the voltaic pile, still the proportions in
which they are present appear to be intimately connected with capability in
the compound of suffering or resisting decomposition. Thus, the
protochloride of tin readily conducts, and is decomposed (402.), but the
perchloride neither conducts nor is decomposed (406.). The protiodide of
tin is decomposed when fluid (402.); the periodide is not (405.). The
periodide of mercury when fused is not decomposed (691.), even though it
does conduct. I was unable to contrast it with the protiodide, the latter
being converted into mercury and periodide by heat.
679. These important differences induced me to look more closely to certain
binary compounds, with a view of ascertaining whether a _law_ regulating
the _decomposability_ according to some _relation of the proportionals or
equivalents_ of the elements, could be discovered. The proto compounds
only, amongst those just referred to, were decomposable; and on referring
to the substances quoted to illustrate the force and generality of the law
of conduction and decomposition which I discovered (402.), it will be found
that all the oxides, chlorides, and iodides subject to it, except the
chloride of antimony and the periodide of mercury, (to which may now
perhaps be added corrosive sublimate,) are also decomposable, whilst many
per compounds of the same elements, not subject to the law, were not so
(405. 406.).
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