Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
717. When the positive and negative electrodes are equal in surface, the
bubbles which rise from them in dilute sulphuric acid are always different
in character. Those from the positive plate are exceedingly small, and
separate instantly from every part of the surface of the metal, in
consequence of its perfect cleanliness (633.); whilst in the liquid they
give it a hazy appearance, from their number and minuteness; are easily
carried down by currents, and therefore not only present far greater
surface of contact with the liquid than larger bubbles would do, but are
retained a much longer time in mixture with it. But the bubbles at the
negative surface, though they constitute twice the volume of the gas at the
positive electrode, are nevertheless very inferior in number. They do not
rise so universally from every part of the surface, but seem to be evolved
at different parts; and though so much larger, they appear to cling to the
metal, separating with difficulty from it, and when separated, instantly
rising to the top of the liquid. If, therefore, oxygen and hydrogen had
equal solubility in, or powers of combining with, water under similar
circumstances, still under the present conditions the oxygen would be far
the most liable to solution; but when to these is added its well-known
power of forming a compound with water, it is no longer surprising that
such a compound should be produced in small quantities at the positive
electrode; and indeed the blenching power which some philosophers have
observed in a solution at this electrode, when chlorine and similar bodies
have been carefully excluded, is probably due to the formation there, in
this manner, of oxywater.
718. That more gas was collected from the wires than from the plates, I
attribute to the circumstance, that as equal quantities were evolved in
equal times, the bubbles at the wires having been more rapidly produced, in
relation to any part of the surface, must have been much larger; have been
therefore in contact with the fluid by a much smaller surface, and for a
much shorter time than those at the plates; hence less solution and a
greater amount collected.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account