Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
[A] For a simple table of correction for moisture, I may take the
liberty of referring to my Chemical Manipulation, edition of 1830,
p. 376.
738. I have not hesitated to apply the term _degree_ (736.), in analogy
with the use made of it with respect to another most important imponderable
agent, namely, heat; and as the definite expansion of air, water, mercury,
&c., is there made use of to measure heat, so the equally definite
evolution of gases is here turned to a similar use for electricity.
739. The instrument offers the only _actual measurer_ of voltaic
electricity which we at present possess. For without being at all affected
by variations in time or intensity, or alterations in the current itself,
of any kind, or from any cause, or even of intermissions of action, it
takes note with accuracy of the quantity of electricity which has passed
through it, and reveals that quantity by inspection; I have therefore named
it a VOLTA-ELECTROMETER.
740. Another mode of measuring volta-electricity may be adopted with
advantage in many cases, dependent on the quantities of metals or other
substances evolved either as primary or as secondary results; but I refrain
from enlarging on this use of the products, until the principles on which
their constancy depends have been fully established (791. 848.);
741. By the aid of this instrument I have been able to establish the
definite character of electro-chemical action in its most general sense;
and I am persuaded it will become of the utmost use in the extensions of
the science which these views afford. I do not pretend to have made its
detail perfect, but to have demonstrated the truth of the principle, and
the utility of the application[A].
[A] As early as the year 1811, Messrs. Gay-Lussac and Thenard employed
chemical decomposition as a measure of the electricity of the voltaic
pile. See _Recherches Physico-chymiques_, p. 12. The principles and
precautions by which it becomes an exact measure were of course not
then known.--_Dec. 1838._
P vi. _On the primary or secondary character of the bodies evolved at the
Electrodes._
742. Before the _volta-electrometer_ could be employed in determining, as a
_general law_, the constancy of electro-decomposition, it became necessary
to examine a distinction, already recognised among scientific men, relative
to the products of that action, namely, their primary or secondary
character; and, if possible, by some general rule or principle, to decide
when they were of the one or the other kind. It will appear hereafter that
great mistakes inspecting electro-chemical action and its consequences have
arisen from confounding these two classes of results together.
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