Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
752. _Nitric acid._--When very strong, it conducted well, and yielded
oxygen at the positive electrode. No gas appeared at the negative
electrode; but nitrous acid, and apparently nitric oxide, were formed
there, which, dissolving, rendered the acid yellow or red, and at last even
effervescent, from the spontaneous separation of nitric oxide. Upon
diluting the acid with its bulk or more of water, gas appeared at the
negative electrode. Its quantity could be varied by variations, either in
the strength of the acid or of the voltaic current: for that acid from
which no gas separated at the _cathode_, with a weak voltaic battery, did
evolve gas there with a stronger; and that battery which evolved no gas
there with a strong acid, did cause its evolution with an acid more dilute.
The gas at the _anode_ was always oxygen; that at the _cathode_ hydrogen.
When the quantity of products was examined by the volta-electrometer
(707.), the oxygen, whether from strong or weak acid, proved to be in the
same proportion as from water. When the acid was diluted to specific
gravity 1.24, or less, the hydrogen also proved to be the same in quantity
as from water. Hence I conclude that the nitric acid does not undergo
electrolyzation, but the water only; that the oxygen at the _anode_ is
always a primary result, but that the products at the _cathode_ are often
secondary, and due to the reaction of the hydrogen upon the nitric acid.
753. _Nitre._--A solution of this salt yields very variable results,
according as one or other form of tube is used, or as the electrodes are
large or small. Sometimes the whole of the hydrogen of the water decomposed
may be obtained at the negative electrode; at other times, only a part of
it, because of the ready formation of secondary results. The solution is a
very excellent conductor of electricity.
754. _Nitrate of ammonia_, in aqueous solution, gives rise to secondary
results very varied and uncertain in their proportions.
755. _Sulphurous acid._--Pure liquid sulphurous acid does not conduct nor
suffer decomposition by the voltaic current[A], but, when dissolved in
water, the solution acquires conducting power, and is decomposed, yielding
oxygen at the _anode_, and hydrogen and sulphur at the _cathode_.
[A] See also De la Rive, Bibliotheque Universelle, tom. xl. p. 205; or
Quarterly Journal of Science, vol. xxvii. p, 407.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account