Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
760. The muriatic acid was gradually diluted. One part with six of water
gave only chlorine at the _anode_. One part with eight of water gave only
chlorine; with nine of water, a little oxygen appeared with the chlorine;
but the occurrence or non-occurrence of oxygen at these strengths depended,
in part, on the strength of the voltaic battery used. With fifteen parts of
water, a little oxygen, with much chlorine, was evolved at the _anode_. As
the solution was now becoming a bad conductor of electricity, sulphuric
acid was added to it: this caused more ready decomposition, but did not
sensibly alter the proportion of chlorine and oxygen.
761. The muriatic acid was now diluted with 100 times its volume of dilute
sulphuric acid. It still gave a large proportion of chlorine at the
_anode_, mingled with oxygen; and the result was the same, whether a
voltaic battery of 40 pairs of plates or one containing only 5 pairs were
used. With acid of this strength, the oxygen evolved at the _anode_ was to
the hydrogen at the _cathode_, in volume, as 17 is to 64; and therefore the
chlorine would have been 30 volumes, had it not been dissolved by the
fluid.
762. Next with respect to the quantity of elements evolved. On using the
volta-electrometer, it was found that, whether the strongest or the weakest
muriatic acid were used, whether chlorine alone or chlorine mingled with
oxygen appeared at the _anode_, still the hydrogen evolved at the _cathode_
was a constant quantity, i.e. exactly the same as the hydrogen which the
_same quantity of electricity_ could evolve from water.
763. This constancy does not decide whether the muriatic acid is
electrolyzed or not, although it proves that if so, it must be in definite
proportions to the quantity of electricity used. Other considerations may,
however, be allowed to decide the point. The analogy between chlorine and
oxygen, in their relations to hydrogen, is so strong, as to lead almost to
the certainty, that, when combined with that element, they would perform
similar parts in the process of electro-decomposition. They both unite with
it in single proportional or equivalent quantities; and the number of
proportionals appearing to have an intimate and important relation to the
decomposability of a body (697.), those in muriatic acid, as well as in
water, are the most favourable, or those perhaps even necessary, to
decomposition. In other binary compounds of chlorine also, where nothing
equivocal depending on the simultaneous presence of it and oxygen is
involved, the chlorine is directly eliminated at the _anode_ by the
electric current. Such is the case with the chloride of lead (395.), which
may be justly compared with protoxide of lead (402.), and stands in the
same relation to it as muriatic acid to water. The chlorides of potassium,
sodium, barium, &c., are in the same relation to the protoxides of the same
metals and present the same results under the influence of the electric
current (402.).
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