Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
868. What, then, follows as a necessary consequence of the whole
experiment? Why, this: that the chemical action upon 32.31 parts, or one
equivalent of zinc, in this simple voltaic circle, was able to evolve such
quantity of electricity in the form of a current, as, passing through
water, should decompose 9 parts, or one equivalent of that substance: and
considering the definite relations of electricity as developed in the
preceding parts of the present paper, the results prove that the quantity
of electricity which, being naturally associated with the particles of
matter, gives them their combining power, is able, when thrown into a
current, to separate those particles from their state of combination; or,
in other words, that _the electricity which decomposes, and that which is
evolved by the decomposition of a certain quantity of matter, are alike._
869. The harmony which this theory of the definite evolution and the
equivalent definite action of electricity introduces into the associated
theories of definite proportions and electrochemical affinity, is very
great. According to it, the equivalent weights of bodies are simply those
quantities of them which contain equal quantities of electricity, or have
naturally equal electric powers; it being the ELECTRICITY which
_determines_ the equivalent number, _because_ it determines the combining
force. Or, if we adopt the atomic theory or phraseology, then the atoms of
bodies which are equivalents to each other in their ordinary chemical
action, have equal quantities of electricity naturally associated with
them. But I must confess I am jealous of the term _atom_; for though it is
very easy to talk of atoms, it is very difficult to form a clear idea of
their nature, especially when compound bodies are under consideration.
870. I cannot refrain from recalling here the beautiful idea put forth, I
believe, by Berzelius (703.) in his development of his views of the
electro-chemical theory of affinity, that the heat and light evolved during
cases of powerful combination are the consequence of the electric discharge
which is at the moment taking place. The idea is in perfect accordance with
the view I have taken of the _quantity_ of electricity associated with the
particles of matter.
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