Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
908. The increase of intensity or power of the current produced by a simple
voltaic circle, with the increase of the force of the chemical action at
the exciting place, is here sufficiently evident. But in order to place it
in a clearer point of view, and to show that the decomposing effect was not
at all dependent, in the latter cases, upon the mere capability of evolving
_more_ electricity, experiments were made in which the quantity evolved
could be increased without variation in the intensity of the exciting
cause. Thus the experiments in which dilute sulphuric acid was used (899.),
were repeated, using large plates of zinc and platina in the acid; but
still those bodies which resisted decomposition before, resisted it also
under these new circumstances. Then again, where nitro-sulphuric acid was
used (906.), mere wires of platina and zinc were immersed in the exciting
acid; yet, notwithstanding this change, those bodies were now decomposed
which resisted any current tending to be formed by the dilute sulphuric
acid. For instance, muriatic acid could not be decomposed by a single pair
of plates when immersed in dilute sulphuric acid; nor did making the
solution of sulphuric acid strong, nor enlarging the size of the zinc and
platina plates immersed in it, increase the power; but if to a weak
sulphuric acid a very little nitric acid was added, then the electricity
evolved had power to decompose the muriatic acid, evolving chlorine at the
_anode_ and hydrogen at the _cathode_, even when mere wires of metals were
used. This mode of increasing the intensity of the electric current, as it
excludes the effect dependent upon many pairs of plates, or even the effect
of making any one acid stronger or weaker, is at once referable to the
condition and force of the chemical affinities which are brought into
action, and may, both in principle and practice, be considered as perfectly
distinct from any other mode.
909. The direct reference which is thus experimentally made in the simple
voltaic circle of the _intensity_ of the electric current to the
_intensity_ of the chemical action going on at the place where the
existence and direction of the current is determined, leads to the
conclusion that by using selected bodies, as fused chlorides, salts,
solutions of acids, &c., which may act upon the metals employed with
different degrees of chemical force; and using also metals in association
with platina, or with each other, which shall differ in the degree of
chemical action exerted between them and the exciting fluid or electrolyte,
we shall be able to obtain a series of comparatively constant effects due
to electric currents of different intensities, which will serve to assist
in the construction of a scale competent to supply the means of determining
relative degrees of intensity with accuracy in future researches[A].
[A] In relation to this difference and its probable cause, see
considerations on inductive polarization, 1354, &c.--_Dec. 1838._
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