Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
968. An arrangement (fig. 84.) was made, in which two glass vessels
contained the same dilute sulphuric acid, sp. gr. 1.25. The plate _z_ was
amalgamated zinc, in connexion, by a platina wire _a_, with the platina
plate _e_; _b_ was a platina wire connecting the two platina plates PP';
_c_ was a platina wire connected with the platina plate P". On the plate
_e_ was placed a piece of paper moistened in solution of iodide of
potassium: the wire _c_ was so curved that its end could be made to rest at
pleasure on this paper, and show, by the evolution of iodine there, whether
a current was passing; or, being placed in the dotted position, it formed a
direct communication with the platina plate _e_, and the electricity could
pass without causing decomposition. The object was to produce a current by
the action of the acid on the amalgamated zinc in the first vessel A; to
pass it through the acid in the second vessel B by platina electrodes, that
its power of decomposing water might, if existing, be observed; and to
verify the existence of the current at pleasure, by decomposition at _e_,
without involving the continual obstruction to the current which would
arise from making the decomposition there constant. The experiment, being
arranged, was examined and the existence of a current ascertained by the
decomposition at _e_; the whole was then left with the end of the wire _c_
resting on the plate _e_, so as to form a constant metallic communication
there.
969. After several hours, the end of the wire _c_ was replaced on the
test-paper at _e_: decomposition occurred, and _the proof_ of a passing
current was therefore complete. The current was very feeble compared to
what it had been at the beginning of the experiment, because of a peculiar
state acquired by the metal surfaces in the second vessel, which caused
them to oppose the passing current by a force which they possess under
these circumstances (1040.). Still it was proved, by the decomposition,
that this state of the plates in the second vessel was not able entirely to
stop the current determined in the first, and that was all that was needful
to be ascertained in the present inquiry.
970. This apparatus was examined from time to time, and an electric current
always found circulating through it, until twelve days had elapsed, during
which the water in the second vessel had been constantly subject to its
action. Notwithstanding this lengthened period, not the slightest
appearance of a bubble upon either of the plates in that vessel occurred.
From the results of the experiment, I conclude that a current _had_ passed,
but of so low an intensity as to fall beneath that degree at which the
elements of water, unaided by any secondary force resulting from the
capability of combination with the matter of the electrodes, or of the
liquid surrounding them, separated from each other.
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