Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
985. Currents of electricity, produced by less than eight or ten series of
voltaic elements, can be reduced to that intensity at which water can
conduct them without suffering decomposition, by causing them to pass
through three or four vessels in which water shall be successively
interposed between platina surfaces. The principles of interference upon
which this effect depends, will be described hereafter (1009. 1018.), but
the effect may be useful in obtaining currents of standard intensity, and
is probably applicable to batteries of any number of pairs of plates.
986. As there appears every reason to expect that all electrolytes will be
found subject to the law which requires an electric current of a certain
intensity for their decomposition, but that they will differ from each
other in the degree of intensity required, it will be desirable hereafter
to arrange them in a table, in the order of their electrolytic intensities.
Investigations on this point must, however, be very much extended, and
include many more bodies than have been here mentioned before such a table
can be constructed. It will be especially needful in such experiments, to
describe the nature of the electrodes used, or, if possible, to select such
as, like platina or plumbago in certain cases, shall have no power of
assisting the separation of the _ions_ to be evolved (913).
987. Of the two modes in which bodies can transmit the electric forces,
namely, that which is so characteristically exhibited by the metals, and
usually called conduction, and that in which it is accompanied by
decomposition, the first appears common to all bodies, although it occurs
with almost infinite degrees of difference; the second is at present
distinctive of the electrolytes. It is, however, just possible that it may
hereafter be extended to the metals; for their power of conducting without
decomposition may, perhaps justly, be ascribed to their requiring a very
high electrolytic intensity for their decomposition.
987-1/2. The establishment of the principle that a certain electrolytic
intensity is necessary before decomposition can be effected, is of great
importance to all those considerations which arise regarding the probable
effects of weak currents, such for instance as those produced by natural
thermo-electricity, or natural voltaic arrangements in the earth. For to
produce an effect of decomposition or of combination, a current must not
only exist, but have a certain intensity before it can overcome the
quiescent affinities opposed to it, otherwise it will be conducted,
producing no permanent chemical effects. On the other hand, the principles
are also now evident by which an opposing action can be so weakened by the
juxtaposition of bodies not having quite affinity enough to cause direct
action between them (913.), that a very weak current shall be able to raise
the sum of actions sufficiently high, and cause chemical changes to occur.
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