Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
990. But it is evident from the principles of definite action already laid
down, that the _quantity_ of electricity in the current cannot be increased
with the increase of the _quantity of metal_ oxidized and dissolved at each
new place of chemical action. A single pair of zinc and platina plates
throws as much electricity into the form of a current, by the oxidation of
32.5 grains of the zinc (868.) as would be circulated by the same
alteration of a thousand times that quantity, or nearly five pounds of
metal oxidized at the surface of the zinc plates of a thousand pairs placed
in regular battery order. For it is evident, that the electricity which
passes across the acid from the zinc to the platina in the first cell, and
which has been associated with, or even evolved by, the decomposition of a
definite portion of water in that cell, cannot pass from the zinc to the
platina across the acid in the second cell, without the decomposition of
the same quantity of water there, and the oxidation of the same quantity of
zinc by it (924. 949.). The same result recurs in every other cell; the
electro-chemical equivalent of water must be decomposed in each, before the
current can pass through it; for the quantity of electricity passed and the
quantity of electrolyte decomposed, _must_ be the equivalents of each
other. The action in each cell, therefore, is not to increase the quantity
set in motion in any one cell, but to aid in urging forward that quantity,
the passing of which is consistent with the oxidation of its own zinc; and
in this way it exalts that peculiar property of the current which we
endeavour to express by the term _intensity_, without increasing the
_quantity_ beyond that which is proportionate to the quantity of zinc
oxidized in any single cell of the series.
991. To prove this, I arranged ten pairs of amalgamated zinc and platina
plates with dilute sulphuric acid in the form of a battery. On completing
the circuit, all the pairs acted and evolved gas at the surfaces of the
platina. This was collected and found to be alike in quantity for each
plate; and the quantity of hydrogen evolved at any one platina plate was in
the same proportion to the quantity of metal dissolved from any one zinc
plate, as was given in the experiment with a single pair (864. &c.). It was
therefore certain, that, just as much electricity and no more had passed
through the series of ten pair of plates as had passed through, or would
have been put into motion by, any single pair, notwithstanding that ten
times the quantity of zinc had been consumed.
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