Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
328. This experiment is neither more nor less than a repetition, in a
refined manner, of that made by Dr. Pearson in 1797[A], and previously by
MM. Paets Van Troostwyk and Deiman in 1789 or earlier. That the experiment
should never be quoted as proving true electro-chemical decomposition, is
sufficiently evident from the circumstance, that the _law_ which regulates
the transference and final place of the evolved bodies (278. 309.) has no
influence here. The water is decomposed at both poles independently of each
other, and the oxygen and hydrogen evolved at the wires are the elements of
the water existing the instant before in those places. That the poles, or
rather points, have no mutual decomposing dependence, may be shown by
substituting a wire, or the finger, for one of them, a change which does
not at all interfere with the other, though it stops all action at the
changed pole. This fact may be observed by turning the machine for some
time; for though bubbles will rise from the point left unaltered, in
quantity sufficient to cover entirely the wire used for the other
communication, if they could be applied to it, yet not a single bubble will
appear on that wire.
[A] Nicholson's Journal, 4to. vol. I. pp. 311, 299. 349.
329. When electro-chemical decomposition takes place, there is great reason
to believe that the _quantity_ of matter decomposed is not proportionate to
the intensity, but to the quantity of electricity passed (320.). Of this I
shall be able to offer some proofs in a future part of this paper (375.
377.). But in the experiment under consideration, this is not the case. If,
with a constant pair of points, the electricity be passed from the machine
in sparks, a certain proportion of gas is evolved; but if the sparks be
rendered shorter, less gas is evolved; and if no sparks be passed, there is
scarcely a sensible portion of gases set free. On substituting solution of
sulphate of soda for water, scarcely a sensible quantity of gas could be
procured even with powerful sparks, and nearly none with the mere current;
yet the quantity of electricity in a given time was the same in all these
cases.
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