Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
337. At the same page of the Bibliotheque Universelle, M. Bonijol is said
to have decomposed, _potash_, and also chloride of silver, by putting them
into very narrow tubes and passing electric sparks from an ordinary machine
over them. It is evident that these offer no analogy to cases of true
voltaic decomposition, where the electricity only decomposes when it is
_conducted_ by the body acted upon, and ceases to decompose, according to
its ordinary laws, when it passes in sparks. These effects are probably
partly analogous to that which takes place with water in Pearson's or
Wollaston's apparatus, and may be due to very high temperature acting on
minute portions of matter; or they may be connected with the results in air
(322.). As nitrogen can combine directly with oxygen under the influence of
the electric spark (324.), it is not impossible that it should even take it
from the potassium of the potash, especially as there would be plenty of
potassa in contact with the acting particles to combine with the nitric
acid formed. However distinct all these actions may be from true polar
electro-chemical decompositions, they are still highly important, and
well-worthy of investigation.
338. The late Mr. Barry communicated a paper to the Royal Society[A] last
year, so distinct in the details, that it would seem at once to prove the
identity in chemical action of common and voltaic electricity; but, when
examined, considerable difficulty arises in reconciling certain of the
effects with the remainder. He used two tubes, each having a wire within it
passing through the closed end, as is usual for voltaic decompositions. The
tubes were filled with solution of sulphate of soda, coloured with syrup of
violets, and connected by a portion of the same solution, in the ordinary
manner; the wire in one tube was connected by a _gilt thread_ with the
string of an insulated electrical kite, and the wire in the other tube by a
similar _gilt thread_ with the ground. Hydrogen soon appeared in the tube
connected with the kite, and oxygen in the other, and in ten minutes the
liquid in the first tube was green from the alkali evolved, and that in the
other red from free acid produced. The only indication of the strength or
intensity of the atmospheric electricity is in the expression, "the usual
shocks were felt on touching the string."
[A] Philosophical Transactions, 1831, p. 165.
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