Experiments and Observations on Different Kinds of AirPriestley, Joseph
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Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
The electric spark taken in any kind of _oil_ produces inflammable air,
as I was led to observe in the following manner. Having found, as will
be mentioned hereafter, that ether doubles the quantity of any kind of
air to which it is admitted; and being at that time engaged in a course
of experiments to ascertain the effect of the electric matter on all the
different kinds of air, I had the curiosity to try what it would do with
_common air_, thus increased by means of ether. The very first spark, I
observed, increased the quantity of this air very considerably, so that
I had very soon six or eight times as much as I began with; and whereas
water imbibes all the ether that is put to any kind of air, and leaves
it without any visible change, with respect to quantity or quality, this
air, on the contrary, was not imbibed by water. It was also very little
diminished by the mixture of nitrous air. From whence it was evident,
that it had received an addition of some other kind of air, of which it
now principally consisted.
In order to determine whether this effect was produced by the _wire_, or
the _cement_ by which the air was confined (as I thought it possible
that phlogiston might be discharged from them) I made the experiment in
a glass syphon, fig. 19, and by that means I contrived to make the
electric spark pass from quicksilver through the air on which I made the
experiment, and the effect was the same as before. At one time there
happened to be a bubble of common air, without any ether, in one part of
the syphon, and another bubble with ether in another part of it; and it
was very amusing to observe how the same electric sparks diminished the
former of these bubbles, and increased the latter.
It being evident that the _ether_ occasioned the difference that was
observable in these two cases, I next proceeded to take the electric
spark in a quantity of ether only, without any air whatever; and
observed that every spark produced a small bubble; and though, while the
sparks were taken in the ether itself, the generation of air was slow,
yet when so much air was collected, that the sparks were obliged to pass
through it, in order, to come to the ether and the quicksilver on which
it rested, the increase was exceedingly rapid; so that, making the
experiment in small tubes, as fig. 16, the quicksilver soon receded
beyond the striking distance. This air, by passing through water, was
diminished to about one third, and was inflammable.
One quantity of air produced in this manner from ether I suffered to
stand two days in water, and after that I transferred it several times
through the water, from one vessel to another, and still found that it
was very strongly inflammable; so that I have no doubt of its being
genuine inflammable air, like that which is produced from metals by
acids, or by any other chemical process.
Public-domain text, read in full here on John Shaqi.
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