Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
Water having this affinity with phlogiston, it is probable that it
always contains a considerable portion of it; which phlogiston having a
stronger affinity with the acid air, which is perhaps the basis of
common air, may by long agitation be communicated to it, so as to leave
it over saturated, in consequence of which it will extinguish a candle.
It is possible, however, that inflammable air and air which extinguishes
a candle may differ from one another in the _mode_ of the combination of
these two constituent principles, as well as in the proportional
quantity of each; and by agitation in water, or long standing, that mode
of combination may change. This we know to be the case with other
substances, as with _milk_, from which, by standing only, _cream_ is
separated; which by agitation becomes _butter_. Also many substances,
being at rest, putrefy, and thereby become quite different from what
they were before. If this be the case with inflammable air, the water
may imbibe either of the constituent parts, whenever any proportion of
it is spontaneously separated from the rest; and should this ever be
that phlogiston, with which air is but slightly overcharged, as by the
burning of a candle, it will be recovered to a state in which a candle
may burn in it again.
It will be observed, however, that it was only in one instance that I
found that strong inflammable air, in its transition to a state in which
it extinguishes a candle, would admit a candle to burn in it, and that
was very faintly; that then the air was far from being pure, as appeared
by the test of nitrous air; and that it was only from a particular
quantity of inflammable air which I got from oak, and which had stood a
long time in water, that I ever got air which was as pure as common air.
Indeed, it is much more easy to account for the passing of inflammable
air into a state in which it extinguishes candles, without any
intermediate state, in which it will admit a candle to burn in it, than
otherwise. This subject requires and deserves farther investigation. It
will also be well worth while to examine what difference the agitation
of air in natural or artificial _sea-water_ will occasion.
Since acid air and phlogiston make inflammable air, and since
inflammable air is convertible into air fit for respiration, it seems
not to be improbable, that these two ingredients are the only essential
principles of common air. For this change is produced by agitation in
water only, without the addition of any fixed air, though this kind of
air, like various other things of a foreign nature, may be combined with
it.
Public-domain text, read in full here on John Shaqi.
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