Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
The fixed air with which our atmosphere abounds may also be supplied by
volcanos, from the vast masses of calcareous matter lodged in the earth,
together with inflammable air. Also a part of it may be supplied from
the fermentation of vegetables upon the surface of it. At present, as
fast as it is precipitated and imbibed by one process, it may be set
loose by others.
Whether there be, upon, the whole, an increase or a decrease of the
general mass of the atmosphere is not easy to conjecture, but I should
imagine that it rather increases. It is true that many processes
contribute to a great visible diminution of common air, and that when by
other processes it is restored to its former wholesomeness, it is not
increased in its dimensions; but volcanos and fires still supply vast
quantities of air, though in a state not yet fit for respiration; and it
will have been seen in my experiments, that vegetable and animal
substances, dissolved by putrefaction, not only emit phlogiston, but
likewise yield a considerable quantity of permanent elastic air,
overloaded indeed with phlogiston, as might be expected, but capable of
being purified by those processes in nature by which other noxious air
is purified.
That particles are continually detaching themselves from the surfaces of
all solid bodies, even the metallic ones, and that these particles
constitute the most permanent part of the atmosphere, as Sir Isaac
Newton supposed, does not appear to me to be at all probable.
My readers will have observed, that not only is common air liable to be
diminished by a mixture of nitrous air, but likewise air originally
produced from inflammable air, and even from nitrous air itself, which
never contained any fixed air. From this it may be inferred, that the
whole of the diminution of common air by phlogiston is not owing to the
precipitation of fixed air, but from a real contraction of its
dimensions, in consequence of its union with phlogiston. Perhaps an
accurate attention to the specific gravity of air procured from these
different materials, and in these different states, may determine this
matter, and assist us in investigating the nature of phlogiston.
In what _manner_ air is diminished by phlogiston, independent of the
precipitation of any of its constituent parts, is not easy to conceive;
unless air thus diminished be heavier than air not diminished, which I
did not find to be the case. It deserves, however, to be tried with more
attention. That phlogiston should communicate absolute _levity_ to the
bodies with which it is combined, is a supposition that I am not willing
to have recourse to, though it would afford an easy solution of this
difficulty.
Public-domain text, read in full here on John Shaqi.
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