Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
When I first repeated your experiment of impregnating water with nitrous
air, the water, I must own tasted acid; as it did in one, or perhaps two
trials afterwards; but, to my great astonishment, in all the following
experiments, though some part of the factitious air, or vapour, was
visibly absorbed by the water, I could not perceive the latter to have
acquired any sensible acidity. I at length found, however, that I could
render this same water _very_ acid, by means only of the nitrous air
already included in the phial with it. Taking the inverted phial out of
the water, I remove my finger from the mouth of it, to admit a little
of the common air, and instantly replace my finger. The redness,
effervescence, and diminution take place. Again taking off my finger,
and instantly replacing it, more common, air rushes in, and the same
phenomena recur. The process sometimes requires to be seven or eight
times repeated, before the whole of the nitrous _vapour_ (as I shall
venture to call it) is condensed into nitrous _acid_, by the successive
entrance of fresh parcels of common air after each effervescence; and
the water becomes evidently more and more acid after every such fresh
admission of the external air, which at length ceases to enter, when the
whole of the vapour has been condensed. No agitation of the water is
requisite, except a gentle motion, just sufficient to rince the sides of
the phial, in order to wash off the condensed vapour.
The acidity which you (and I likewise, at first) observed in the water
agitated with nitrous air _alone_, I account for thus. On bringing the
phial to the mouth, the common air meeting with the nitrous vapour in
the neck of the phial, condenses it, and impregnates the water with the
acid, in the very act of receiving it upon the tongue. On stopping the
mouth of the phial with my tongue for a short time and afterwards
withdrawing it a very little, to suffer the common air to rush past it
into the phial, the sensation of acidity has been sometimes intolerable:
but taking a large gulph of the water at the same time, it has been
found very slightly acid.--The following is one of the methods by which
I have given water a very strong acid impregnation, by means of a
mixture of nitrous and common air.
Into a small phial, containing only common air, I force a quantity of
nitrous air at random, out of a bladder, and instantly clap my finger on
the mouth of the bottle. I then immerse the neck of it into water, a
small quantity of which I suffer to enter, which squirts into it with
violence; and immediately replacing my finger, remove the phial. The
water contained in it is already _very_ acid, and it becomes more and
more so (if a sufficient quantity of nitrous air was at first thrown in)
on alternately stopping the mouth of the phial, and opening it, as often
as fresh air will enter.
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