Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
A piece of _alum_ exposed to this air turned yellow, absorbed it as fast
as the saltpetre had done, and was reduced by it to the form of a
powder. Common salt, as might be expected, had no effect whatever on
this marine acid air.
I had also imagined, that if air diminished by the processes
above-mentioned was affected in this manner, in consequence of its being
saturated with phlogiston, a mixture of this acid air might imbibe that
phlogiston, and render it wholesome again; but I put about one fourth of
this air to a quantity of air in which metals had been calcined, without
making any sensible alteration in it. I do not, however, infer from
this, that air is not diminished by means of phlogiston, since the
common air, like some other substances, may hold the phlogiston too
fast, to be deprived of it by this acid air.
I shall conclude my account of these experiments with observing, that
the electric spark is visible in acid air, exactly as it is in common
air; and though I kept making this spark a considerable time in a
quantity of it, I did not perceive that any sensible alteration was made
in it. A little inflammable air was produced, but not more than might
have come from the two iron nails which I made use of in taking the
sparks.
FOOTNOTES:
[9] It will be seen, in the second part of this work, that, in some of
these processes, I had afterwards more success.
SECTION X.
MISCELLANEOUS OBSERVATIONS.
1. As many of the preceding observations relate to the _vinous_ and
_putrefactive_ fermentations, I had the curiosity to endeavour to
ascertain in what manner the air would be affected by the _acetous_
fermentation. For this purpose I inclosed a phial full of small beer in
a jar standing in water; and observed that, during the first two or
three days, there was an increase of the air in the jar, but from that
time it gradually decreased, till at length there appeared to be a
diminution of about one tenth of the whole quantity.
During this time the whole surface of it was gradually covered with a
scum, beautifully corrugated. After this there was an increase of the
air till there was more than the original quantity; but this must have
been fixed air, not incorporated with the rest of the mass; for,
withdrawing the beer, which I found to be sour, after it had stood 18 or
20 days under the jar, and passing the air several times through cold
water, the original quantity was diminished about one ninth. In the
remainder a candle would not burn, and a mouse would have died
presently.
The smell of this air was exceedingly pungent, but different from that
of the putrid effluvium. A mouse lived perfectly well in this air, thus
affected with the acetous fermentation; after it had stood several days
mixed with four times the quantity of fixed air.
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