Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
It was upon this idea, together with others similar to it, that I took
so much pains to mix fixed air with air diminished by respiration or
putrefaction, in order to make it fit for respiration again; and I
thought that I had, in general, succeeded to a considerable degree, p.
99, &c. I will add, also, what I did not mention before, that I once
endeavoured, but without effect, to preserve mice alive in the same
unchanged air, by supplying them with fixed air, when the air in which
they were confined began to be injured by their respiration. Without
effect, also, I confined for some months, a quantity of quick lime in a
given quantity of common air, thinking it might extract the fixed air
from it.
The experiments which I made with electricity were solely intended to
ascertain what has often been attempted, but, as far as I know, had
never been fully accomplished, viz. to change the blue colour of
liquors, tinged with vegetable juices, red.
For this purpose I made use of a glass tube, about one tenth of an inch
diameter in the inside, as in fig. 16. In one end of this I cemented a
piece of wire _b_, on which I put a brass ball. The lower part from _a_
was filled with water tinged blue, or rather purple, with the juice of
turnsole, or archil. This is easily done by an air-pump, the tube being
set in a vessel of the tinged water.
Things being thus prepared, I perceived that, after I had taken the
electric spark, between the wire _b_, and the liquor at _a_, about a
minute, the upper part of it began to look red, and in about two minutes
it was very manifestly so; and the red part, which was about a quarter
of an inch in length, did not readily mix with the rest of the liquor. I
observed also, that if the tube lay inclined while I took the sparks,
the redness extended twice as far on the lower side as on the upper.
The most important, though the least expected observation, however, was
that, in proportion as the liquor became red, it advanced nearer to the
wire, so that the space of air in which the sparks were taken was
diminished; and at length I found that the diminution was about one
fifth of the whole space; after which more electrifying produced no
sensible effect.
To determine whether the cause of the change of colour was in the _air_,
or in the _electric matter_, I expanded the air which had been
diminished in the tube by means of an air-pump, till it expelled all the
liquor, and admitted fresh blue liquor into its place; but after that,
electricity produced no sensible effect, either on the air, or on the
liquor; so that it was evident that the electric matter had decomposed
the air, and had made it deposite something that was of an acid nature.
In order to determine whether the _wire_ had contributed any thing to
this effect, I used wires of different metals, iron, copper, brass, and
silver; but the result was the very same with them all.
Public-domain text, read in full here on John Shaqi.
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