Experiments and Observations on Different Kinds of AirPriestley, Joseph
History
Experiments and Observations on Different Kinds of Air
Priestley, Joseph
Air -- Early works to 1800; Chemistry -- Early works to 1800
If the whole of the diminution of common air was produced by the
deposition of fixed air, it would be easy to ascertain the quantity of
fixed air that is contained in any given quantity of common air. But it
is evident that the whole of the diminution of common air by phlogiston
is not owing to the precipitation of fixed air, because a mixture of
nitrous air will make a great diminution in all kinds of air that are
fit for respiration, even though they never were common air, and though
nothing was used in the process for generating them that can be supposed
to yield fixed air.
Indeed, it appears, from some of the experiments, that the diminution of
some of these kinds of air by nitrous air is so great, and approaches so
nearly to the quantity of the diminution of common air by the same
process, as to shew that, unless they be very differently affected by
phlogiston, very little is to be allowed to the loss of fixed air in the
diminution of common air by nitrous air.
The kinds of air on which this experiment was made were inflammable air,
nitrous air diminished by iron filings and brimstone, and nitrous air
itself; all of which are produced by the solution of metals in acids;
and also on common air diminished and made noxious, and therefore
deprived of its fixed air by phlogistic processes; and they were
restored to a great degree of purity by agitation in water, out of which
its own air had been carefully boiled.
To five parts of inflammable air, which had been agitated in water till
it was diminished about one half (at which time part of it fired with a
weak explosion) I put one part of nitrous air, which diminished it one
eighth of the whole. This was done in lime-water, without any
precipitation of lime. To compare this with common air, I mixed the same
quantity, viz. five parts of this, and one part of nitrous air: when
considerable crust of lime was formed upon the surface of the lime
water, though the diminution was very little more than in the former
process. It is possible, however, that the common air might have taken
more nitrous air before it was fully saturated, so as to begin to
receive an addition to its bulk.
I agitated in water a quantity of nitrous air phlogisticated with iron
filings and brimstone, and found it to be so far restored, that three
fourths of an ounce measure of nitrous air being put to two ounce
measures of it, made no addition to it.
But the most remarkable of these experiments is that which I made with
_nitrous air_ itself which I had no idea of the possibility of reducing
to a state fit for respiration by any process whatever, at the time of
my former publication on this subject. This air, however, itself,
without any previous phlogistication, is purified by agitation in water
till it is diminished by fresh nitrous air, and to a very considerable
degree.
Public-domain text, read in full here on John Shaqi.
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