Field's Chromatography: or Treatise on Colours and Pigments as Used by ArtistsField, George
Science
Field's Chromatography: or Treatise on Colours and Pigments as Used by Artists
Field, George
Color; Colors; Painting -- Technique
_Litharge_ is merely fused massicot. Old writers speak of litharge of
silver and litharge of gold, oxides of lead, pale and reddish yellow
respectively. Commercial litharge, especially that which is foreign,
contains sometimes a considerable proportion of oxide of copper and
iron. The principal impurity, however, is generally silica, left
undissolved on treating the litharge with nitric or acetic acid.
Litharge is commonly used in preparing drying oils, which contain a
greater or less amount of the oxide in the form of oleate of lead. Oils
made siccative by means of litharge are therefore liable to be damaged
by foul gas. It is a matter of congratulation that such injury is not
lasting, and that the oil, like white lead, recovers its original colour
on exposure to air and light. Some drying oil which we exposed on a tile
to an atmosphere of sulphuretted hydrogen until it was completely
blackened, regained its former yellow hue on being submitted for a day
or so to air and light. Hence, although the employment of lead as a
siccative is not desirable, its effects are not so deleterious as might
be imagined.
61. _Patent Yellow_,
_Turner's Yellow_, _Montpellier Yellow_, _Mineral Yellow_, _Cassel
Yellow_, &c., is a mixture of chloride and oxide of lead, obtainable
either as a pale or a deep yellow. It is a hard, ponderous, sparkling
substance, of a crystalline texture and bright colour; hardly inferior,
when ground, to chrome yellow. Of an excellent body, and working well in
oil and water, but soon injured both by the sun's light and impure air.
A variety, mentioned by Mérimée, in which bismuth and antimony are also
used, is of greater durability.
62. _Platinum Yellow._
Our own opinion of this costly preparation is that the good qualities of
the product do not justify its price. It may be obtained as a bright,
rich, deep yellow, of considerable transparency; but the colour is acted
upon by foul gas and exposure. Even in a book we have found it assume a
dirty greyish cast, and a specimen which had been kept in a drawer,
wrapped up in paper, became perfectly black in a few years. The presence
of palladium interferes with the beauty of the original tint, but does
not affect its stability.
63. _Thallium Yellow._
The new metal thallium yields in combination with chromic acid two
yellow colours, a pale and an orange. They are not absolutely insoluble
in water, and the sulphide of thallium being brown, would probably be
damaged by impure air. But whatever their properties as pigments may be,
their habitudes as such are not yet known. The present scarcity of the
metal renders the colours produced from it mere scientific curiosities.
64. _Thwaites' Yellow._
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