Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendixBattershall, Jesse P. (Jesse Park)
Science
Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendix
Battershall, Jesse P. (Jesse Park)
Food adulteration and inspection; Food adulteration and inspection -- United States
Another objection to the use of alum is that it is frequently employed
for the purpose of disguising the bad quality of damaged and inferior
grades of flour. The presence of copper salts in bread is of rare
occurrence. Their detection is accomplished by treating a portion
of the crumb with a dilute solution of potassium ferrocyanide
acidulated with acetic acid, which, in presence of copper, will impart
a reddish-brown colour to the bread. If contained in any appreciable
proportion, it can be extracted from the ash obtained by the
incineration of the bread, and deposited upon the interior of a weighed
platinum capsule by the electrolytic method.
_Starch_ (C_{6}H_{10}O_{5}).--Starch, which enters so largely into the
composition of cereals, is a carbo-hydrate, _i. e._ hydrogen and oxygen
are contained in the proportions necessary to form water. In this
respect, it is identical with woody fibre, cellulose, and dextrine.
The well-known dark-blue colour produced upon the addition of a
solution of iodine to starch-paste forms the usual qualitative test
for its presence. This coloration is discharged by alkalies and by a
solution of sulphurous acid. The quantitative estimation of starch in
mixtures is best effected by heating the dry substance in a closed
tube for 24 hours, together with a dilute hot alcoholic solution of
potassium hydroxide. The hot liquid is next filtered, the residue
washed with alcohol, and the filtrate heated with 2 per cent. solution
of hydrochloric acid until it ceases to show the blue coloration when
tested with iodine. It is then rendered alkaline, and the proportion of
starch originally present, calculated from the amount of sugar formed,
as determined by Fehling’s solution. Although identical in chemical
composition, the various forms of starch met with in the vegetable
kingdom vary in size and exhibit characteristic differences in the
appearance of the granules. The following are measurements of several
varieties of starch granules:--
Millimetre.
Wheat ·0500
Rye ·0310
Rice ·0220
Corn ·0300
Bean ·0631
Potato ·1850
The larger granules of potato starch, when suspended in water, subside
more rapidly than those of wheat starch; they are also far more readily
ruptured.
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