Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendixBattershall, Jesse P. (Jesse Park)
Science
Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendix
Battershall, Jesse P. (Jesse Park)
Food adulteration and inspection; Food adulteration and inspection -- United States
in which P is the total rotation observed. Upon now treating the
solution of glucose with an excess of an alkaline solution of mercuric
cyanide (prepared by dissolving 120 grammes of mercuric cyanide and 25
grammes of potassium hydroxide in 1 litre of water), the dextrose and
maltose contained in the sample are decomposed, leaving the dextrine
unaffected. A second polariscopic reading is then made, which gives the
amount of dextrine present, that is
P´ = 193 _d´_, (2)
from which the proportion of dextrine is calculated.
Subtracting the second equation from the first, we have
P - P´ = 52 _d_ + 139 _m_. (3)
Both dextrose and maltose reduce Fehling’s solution, the total
reduction (R) being the reducing per cent. of the former (_d_) added to
that of the latter (_m_). The reducing power of maltose is, however,
only 0·62 as compared with dextrine, therefore
R = _d_ + 0·62 _m_. (4)
Multiplying by 52, we have
52 R = 52 _d_ + 32·24 _m_,
and subtract from (3), which gives
P - P´ - 52 R = 106·76 _m_, (5)
whence
_m_ = (P - P´ - 52 R) / 106·76 (6)
_d_ = R - 0·62 _m_ (7)
and
_d´_ = P´/193.
FOOTNOTES:
[54] It is of interest in this connection to note the recent discovery
of a coal-tar derivative, benzoyle sulphonic imide, C_{6}H_{4} <CO/SO>
NH, commercially known as “saccharine.” This body possesses about
230 times the sweetening power of cane sugar. It bears, however, no
near chemical relation to the sugars, which, for the greater part,
constitute hexatomic alcohols. See Amer. Chem. Jour., i. p. 170, and
vol. ii. p. 181; also, Jour. Soc. Chem. Indus., No. 2, vol. vi. p. 75.
[55] Of 41 samples of molassan, tested in Massachusetts in 1885, 12
contained tin chloride.
[56] The average composition of over 100,000 samples of raw cane sugar
(mostly Cuban) tested in the United States Laboratory during the past
five years, has been as follows:--
Per cent.
Moisture 3·0
Ash 1·5
Polarisation 90°
[57] The foregoing description of the polariscope was embodied in
an article contributed by the author to Van Nostrand’s Engineering
Magazine.
[58] Journ. Amer. Chem. Soc., i. p. 1.
[59] Wiley, Chem. News, xlvi. p. 175.
HONEY.
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