Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
in ink of which the manufacturer's name was known
as well as his formula and only thirty years old
showed evidence of considerable "browning;" some
of them when tested in juxtaposition with those of
from fifty to one hundred years old which had turned
completely brown, gave approximately the same results,
and differentiated largely from the results obtained
from jet black specimens of eighty to five
hundred or more years of age. In a number of the
browner ones indigo was found to be present while in
many of the black ones it was not, demonstrating
that the reason for the continuing blackness of the
older inks is not due to an added color or pigment of
any kind and furthermore that the "Stark" and
corresponding ink formulas after the test of TIME did not
retain their original blackness but deteriorated to a
brown color; moreover, that their purpose as in the
present day was to give an agreeable and immediate
color result, a free-flowing ink, and to cheapen the
cost of manufacture when compared with that of an
unadulterated tanno-gallate of iron ink.
No disagreement being now possible as to the lasting
color virtues of a properly proportioned tanno-
gallate of iron ink WITHOUT an "added" color or
pigment, there remained the sole question as to the
vehicle utilized to hold this combination in suspension
and whether or not it had to do with the continuing
blackness of the older inks.
The answer must lie between the vegetable product
known as gum and the animal product known as
gelatine. The first disintegrates, quickly absorbs
moisture and gradually disappears, while gelatine
(isinglass) "contains under conditions 50% carbon,
although its molecular formula has not yet been
determined. It cannot be converted into vapor and
does not form well-defined compounds with other
bodies; it is insoluble in alcohol which precipitates it
in flakes from its aqueous solution. It is also precipitated
by tannin, which combines with it to form
an insoluble non-putrescible compound. Gallic acid,
however, does not precipitate it." (Bloxam.)
Possessing an undisturbed and complete history it
was the very substance employed long before the discovery
of gall ink, and is found present in the earliest
specimens of the "Indian" inks which remain to us.
It must now be evident that there can be no material
difference of opinions as to what has been so
clearly and conclusively established, viz. that ink
which contains a base of tanno-gallate of iron (without
"added" color) is a permanent ink, and the
length of its durability and continuing pristineness
can be disturbed only by inferior quality of constituents,
wrong methods of admixture and its future
environment. Hence any black ink with this combination
missing is of no practical value whatever
either for record or commercial uses.
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