Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
"The action which takes place when moist vegetable
substances are exposed to oxygen is that of
slow combustion ('eremacausis'), the oxygen
uniting with the wood and liberating a volume of
carbonic acid equal to itself, and another portion
combining with the hydrogen of the wood to form
water. Decomposition takes place on contact with
a body already undergoing the same change, in the
same manner that yeast causes fermentation. Animal
matter enters into combination with oxygen in
precisely the same way as vegetable matter, but as,
in addition to carbon and hydrogen, it contains nitrogen,
the products of the eremacausis are more
numerous, being carbon and nitrate of ammonia,
carburetted and sulphuretted hydrogen, and water,
and these ammoniacal salts greatly favor the growth
of fungi. Now paper consists essentially of woody
fibre, having animal matter as size on its surface.
The first microscopic symptom of decay in paper is
irregularity of surface, with a slight change of color,
indicating the commencement of the process just
noticed, during which, in addition to carbonic acid,
certain organic acids are formed, as crenic and ulmic
acids, which, if the paper has been stained by
a coloring matter, will form spots of red on the
surface. The same process of decay goes on in
parchment as in paper, only with more rapidity,
from the presence of nitrogen in its composition.
When this decay has begun to take place, fungi are
produced, the most common species being
Penicilium glaucum. They insinuate themselves between
the fibre, causing a freer admission of air, and
consequently hasten the decay. The substances most
successfully used as preventives of decay are the
salts of mercury, copper, and zinc. Bichloride of
mercury (corrosive sublimate) is the material employed
in the kyanization of timber, the probable
mode of action being its combination with the albumen
of the wood, to form an insoluble compound
not susceptible of spontaneous decomposition, and
therefore incapable of exciting fermentation. The
antiseptic power of corrosive sublimate may be
easily tested by mixing a little of it with flour
paste, the decay of which, and the appearance of
fungi, are quite prevented by it. Next to corrosive
sublimate in antiseptic value stand the salts of
copper and zinc. For use in the preservation of
paper the sulphate of zinc is better than the chloride,
which is to a certain extent delinquescent."
There are numerous paper tests which include the
matter of sizing, direction of the grain, absorbing
powers, character of ingredients, etc. A few of them
are cited.
Public-domain text, read in full here on John Shaqi.
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